.alpha.-L-Tagatofuranose, 1,2:4,6-bis-O-(1-methylethylidene)-

Base Information

Chemical Name:.alpha.-L-Tagatofuranose, 1,2:4,6-bis-O-(1-methylethylidene)-
CAS No.:151377-79-6
Molecular Formula:C₁₂H₂₀O₆
Molecular Weight:260.287
Hs Code.:
Mol file:151377-79-6.mol

Synonyms:Spiro[1,3-dioxolane-4,6'-[6H]furo[3,2-d][1,3]dioxin],a-L-tagatofuranose deriv.

Suppliers and Price of .alpha.-L-Tagatofuranose, 1,2:4,6-bis-O-(1-methylethylidene)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of .alpha.-L-Tagatofuranose, 1,2:4,6-bis-O-(1-methylethylidene)-

Chemical Property:

PSA：66.38000
LogP:0.37680

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of .alpha.-L-Tagatofuranose, 1,2:4,6-bis-O-(1-methylethylidene)-

There total 1 articles about .alpha.-L-Tagatofuranose, 1,2:4,6-bis-O-(1-methylethylidene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18604-19-8,62133-03-3
11,2:4,6-di-O-isopropylidene-α-L-sorbofuranose

: 151377-79-6,62133-03-3
1,2:4,6-Di-O-isopropylidene-α-L-tagatofuranose

Guidance literature:: With sodium tetrahydroborate; dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride; Yield given. Multistep reaction; 1.) CH₂Cl₂, 2.) EtOH;
DOI:10.1016/S0040-4039(00)73649-5

Reference yield: 85.0%

: 151377-79-6,62133-03-3
1,2:4,6-Di-O-isopropylidene-α-L-tagatofuranose

: 151377-80-9
1,2:3,4-Di-O-isopropylidene-α-L-tagatofuranose

Guidance literature:: With camphor-10-sulfonic acid; In acetone;
DOI:10.1016/S0040-4039(00)73649-5

Reference yield:

: 151377-79-6,62133-03-3
1,2:4,6-Di-O-isopropylidene-α-L-tagatofuranose

: Acetic acid (3aR,6S,6aR)-4-acetoxymethyl-6-azidomethyl-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / camphersulfonic acid / acetone

2: Et₃N / CH₂Cl₂

3: NaN₃ / dimethylsulfoxide / 80 °C

4: BF₃*OEt₂ / 0 °C

With sodium azide; camphor-10-sulfonic acid; boron trifluoride diethyl etherate; triethylamine; In dichloromethane; dimethyl sulfoxide; acetone;
DOI:10.1016/S0040-4039(00)73649-5