2,2,3,3-Tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane

Base Information

Chemical Name:2,2,3,3-Tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane
CAS No.:151460-00-3
Molecular Formula:C₂₈H₅₆O₄
Molecular Weight:456.75
Hs Code.:
DSSTox Substance ID:DTXSID20566259
Nikkaji Number:J563.800C
Mol file:151460-00-3.mol

Synonyms:151460-00-3;2,2,3,3-TETRAMETHYL-9-TETRADECYL-1,4,8,11-TETRAOXACYCLOTETRADECANE;9-TETRADECYL-2,2,3,3-TETRAMETHYL-1,4,8,11-TETRAOXACYCLOTETRADECANE;SCHEMBL5854393;DTXSID20566259

Suppliers and Price of 2,2,3,3-Tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of 2,2,3,3-Tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane

Chemical Property:

PSA：36.92000
LogP:7.86360
XLogP3:8.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:13
Exact Mass:456.41786026
Heavy Atom Count:32
Complexity:422

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCCCCCCCCC1COCCCOC(C(OCCCO1)(C)C)(C)C

Technology Process of 2,2,3,3-Tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane

There total 4 articles about 2,2,3,3-Tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.3%

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 156210-20-7
5-tetradecyl-4,7-dioxa-1,10-decanediol bis-p-toluenesulfonate

: 151460-00-3
2,2,3,3-tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane

Guidance literature:: In N,N-dimethyl-formamide; for 72h; Heating;
DOI:10.1021/ac00071a012

Reference yield:

: 6920-24-7
hexadecane-1,2-diol

: 151460-00-3
2,2,3,3-tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane

Guidance literature:: Multi-step reaction with 4 steps

1: 16.5 percent / NaH / dimethylformamide / 1.) 50 deg C, 30 min, 2.) 80 deg C, 24 h

2: 1.) NaBH₄, BF₃*Et₂O, 2.) 30percent H₂O₂, NaOH / 1.) THF, room temperature, 24 h, 2.) water, 2 h

3: 58 percent

4: 4.3 percent / dimethylformamide / 72 h / Heating

With sodium hydroxide; sodium tetrahydroborate; boron trifluoride diethyl etherate; dihydrogen peroxide; sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1021/ac00071a012

Reference yield:

: 151331-30-5
5-tetradecyl-4,7-dioxa-1,9-decadiene

: 151460-00-3
2,2,3,3-tetramethyl-9-tetradecyl-1,4,8,11-tetraoxacyclotetradecane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) NaBH₄, BF₃*Et₂O, 2.) 30percent H₂O₂, NaOH / 1.) THF, room temperature, 24 h, 2.) water, 2 h

2: 58 percent

3: 4.3 percent / dimethylformamide / 72 h / Heating

With sodium hydroxide; sodium tetrahydroborate; boron trifluoride diethyl etherate; dihydrogen peroxide; In N,N-dimethyl-formamide;
DOI:10.1021/ac00071a012