digallium sodium dioxide

Base Information

• Chemical Name: digallium sodium dioxide
• CAS No.: 12063-93-3
• Molecular Formula: GaO₂*Na
• Molecular Weight: 124.712
• Mol file: 12063-93-3.mol

Synonyms:Galliumsodium oxide (NaGaO2) (8CI); Sodium gallate (NaGaO2) (6CI,7CI); Gallium sodiumoxide (GaNaO2); Sodium gallium oxide (GaNaO2); Sodium gallium oxide (NaGaO2)

Chemical Property of digallium sodium dioxide

Chemical Property:

• PSA: 0.00000
• LogP: -0.28090

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of digallium sodium dioxide

There total 10 articles about digallium sodium dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3Na(1+)*6HCO2(1-)*Ga(3+)=Na3Ga(HCO2)6 → gallium(III) oxide + sodium gallium oxide (12063-93-3) + sodium carbonate (497-19-8)

Guidance literature:

In neat (no solvent, solid phase); NaGa-compound heated to 600°C at 10°C/min in air; monitored by XRD;

DOI:10.1016/j.molstruc.2009.08.009

Reference yield:

decasodium bis(hexahydroxogallate) tetrahydroxide → sodium gallium oxide (12063-93-3) + water (7732-18-5) + sodium hydroxide (1310-73-2)

Guidance literature:

In neat (no solvent); heating (135°C);

DOI:10.1002/zaac.19976230925

Reference yield:

gallium(III) oxide + sodium carbonate (497-19-8) → sodium gallium oxide (12063-93-3)

Guidance literature:

In neat (no solvent); byproducts: CO2; starting materials mixed, ground, heated to 673K, temp. raised at 100K/h to 973K, left overnight;

DOI:10.1111/j.1151-2916.1990.tb05269.x

upstream raw materials:

sodium carbonate

Refernces

• 1、 Zhou, Shi-Xiong,Lv, Xiao-Jun,Zhang, Chen,Huang, Xing,Kang, Lei,Lin, Zhe-Shuai,Chen, Yong,Fu, Wen-Fu. "Synthesis of NiGa2O4 octahedron nanocrystal with exposed {111} facets and enhanced efficiency of photocatalytic water splitting". . p. 223 - 230. Retrieved 2015.
• 2、 Nagatani, Hiraku,Suzuki, Issei,Kita, Masao,Tanaka, Masahiko,Katsuya, Yoshio,Sakata, Osami,Miyoshi, Shogo,Yamaguchi, Shu,Omata, Takahisa. "Structural and thermal properties of ternary narrow-gap oxide semiconductor; Wurtzite-derived β-CuGaO2". . p. 1698 - 1704. Retrieved 2015.
• 3、 Vanaja,Ajimsha,Asha,Jayaraj. "P -type electrical conduction in α-AgGaO2 delafossite thin films". . . Retrieved 2006.
• 4、 Zhao, Meiming,Gu, Yaliu,Chen, Ping,Xin, Zhenyu,Zhu, Heng,Wang, Bing,Zhu, Kai,Yan, Shicheng,Zou, Zhigang. "Highly selective electrochemical CO2 reduction to CO using a redox-active couple on low-crystallinity mesoporous ZnGa2O4 catalyst". . p. 9316 - 9323. Retrieved 2019.
• 5、 Maruyama, Yoshihiko,Irie, Hiroshi,Hashimoto, Kazuhito. "Visible light sensitive photocatalyst, delafossite structured α-AgGaO2". . p. 23274 - 23278. Retrieved 2006.
• 6、 Yan, Shi Cheng,Ouyang, Shu Xin,Gao, Jun,Yang, Ming,Feng, Jian Yong,Fan, Xiao Xing,Wan, Li Juan,Li, Zhao Sheng,Ye, Jin Hua,Zhou, Yong,Zou, Zhi Gang. "A room-temperature reactive-template route to mesoporous znga 2o4 with improved photocatalytic activity in reduction of co2". . p. 6400 - 6404. Retrieved 2010.