1,3,4,6-Tetra-O-benzoyl-a-D-fructofuranose

Base Information

• Chemical Name: 1,3,4,6-Tetra-O-benzoyl-a-D-fructofuranose
• CAS No.: 58670-14-7
• Molecular Formula: C₁₆H₂₂O₁₁
• Molecular Weight: 390.344
• Mol file: 58670-14-7.mol

Synonyms:1,3,4,6-Tetra-O-benzoyl-a-D-fructofuranose

Chemical Property of 1,3,4,6-Tetra-O-benzoyl-a-D-fructofuranose

Chemical Property:

• PSA: 134.66000
• LogP: 4.23900

Purity/Quality:

95% ^*data from raw suppliers

1,3,4,6-Tetra-O-benzoyl-a-D-fructofuranose ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3,4,6-Tetra-O-benzoyl-a-D-fructofuranose

There total 6 articles about 1,3,4,6-Tetra-O-benzoyl-a-D-fructofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

D-fructose pentaacetate (847612-42-4) → 1,2,3,4,6-Penta-O-acetyl-α-D-fructofuranose (58670-14-7) + 2,3,4,6-tetra-O-acetyl-β-D-fructofuranose

Guidance literature:

With Candida rugosa lipase; butan-1-ol; In various solvent(s); at 45 ℃; for 7h; Enzymatic reaction;

DOI:10.1016/j.carres.2004.11.003

Reference yield:

D-fructose (470-23-5,470-24-6,10247-46-8,10489-79-9,35673-97-3,36441-90-4,36441-92-6,36468-68-5,37500-17-7,40461-86-7,40461-87-8,41579-20-8,41846-98-4,41846-99-5,41847-00-1,41847-01-2,41847-02-3,41847-03-4,41847-04-5,41847-05-6,41847-06-7,41847-51-2,41847-52-3,42744-42-3) → 1,2,3,4,6-Penta-O-acetyl-α-D-fructofuranose (58670-14-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 95 percent / Candida antartica B lipase / tetrahydrofuran / 2 h / 45 °C / Enzymatic reaction

2: 98 percent / pyridine / 6 h / 20 °C

3: Candida rugosa lipase; butanol / various solvent(s) / 7 h / 45 °C / Enzymatic reaction

With Candida antartica B lipase; Candida rugosa lipase; butan-1-ol; In tetrahydrofuran; pyridine;

DOI:10.1016/j.carres.2004.11.003

Reference yield:

1,6-di-O-acetyl-D-fructofuranose → 1,2,3,4,6-Penta-O-acetyl-α-D-fructofuranose (58670-14-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / pyridine / 6 h / 20 °C

2: Candida rugosa lipase; butanol / various solvent(s) / 7 h / 45 °C / Enzymatic reaction

With Candida rugosa lipase; butan-1-ol; In pyridine;

DOI:10.1016/j.carres.2004.11.003

upstream raw materials:

D-fructose pentaacetate

D-fructose

fructose

acetic anhydride

Downstream raw materials:

fructose

L-iditol hexaacetate

1,2,3,4,5,6-hexa-O-acetyl-D-glucitol

L-iditol