O-(tert-Butyldimethylsilyl)hydroxylamine

Base Information

Chemical Name:O-(tert-Butyldimethylsilyl)hydroxylamine
CAS No.:41879-39-4
Molecular Formula:C6H17NOSi
Molecular Weight:147.293
Hs Code.:2931900090
European Community (EC) Number:623-284-3
ChEMBL ID:CHEMBL4174906
DSSTox Substance ID:DTXSID00405612
Nikkaji Number:J1.867.217K
Wikidata:Q82210246
Mol file:41879-39-4.mol

Synonyms:O-(tert-Butyldimethylsilyl)hydroxylamine;41879-39-4;O-[tert-butyl(dimethyl)silyl]hydroxylamine;O-(t-butyldimethylsilyl)hydroxylamine;o-t-butyldimethylsilyl hydroxylamine;O-tert-butyldimethylsilylhydroxylamine;O-(tert-Butyldiemthylsilyl)hydroxylamine;O-(tert-Butyldimethyl-silyl)hydroxylamine;O-(tert-Butyldimethylsilyl)hydroxylamine, 95%;Aminoxy-tert-butyldimethylsilane;H2N-OTBS;TBS-ONH2;SCHEMBL314434;Hydroxylamine, TBDMS derivative;CHEMBL4174906;DTXSID00405612;o-t-butyldimethylsilylhydroxylamine;MFCD00054944;(Aminooxy) (tert-butyl)dimethylsilane;AKOS000280546;o-(t-Butyldimethylsilyl)hydroxyl-amine;0-(tert-butyldimethylsilyl)hydroxylamine;o-(tert-butyldimethylsilyl)-hydroxylamine;AS-79127;o-(tert-butyl dimethyl silyl)hydroxylamine;O-(tert-butyldimethyl-silyl) hydroxylamine;CS-0343137;FT-0690486;F87305;?O-(TERT-BUTYLDIMETHYLSILYL)HYDROXYLAMINE;O-(tert-Butyldimethylsilyl)hydroxylamine, 90+%;A848071

Suppliers and Price of O-(tert-Butyldimethylsilyl)hydroxylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
O-(tert-Butyldimethylsilyl)hydroxylamine 95%
5g
$ 427.00

Sigma-Aldrich
O-(tert-Butyldimethylsilyl)hydroxylamine 95%
1g
$ 89.90

Matrix Scientific
O-(tert-Butyldimethylsilyl)hydroxylamine 95%
25g
$ 1980.00

Matrix Scientific
O-(tert-Butyldimethylsilyl)hydroxylamine 95%
10g
$ 990.00

Alfa Aesar
O-(tert-Butyldimethylsilyl)hydroxylamine, 90+%
1g
$ 83.40

Alfa Aesar
O-(tert-Butyldimethylsilyl)hydroxylamine 90+%
0.25g
$ 27.90

AK Scientific
O-(Tert-Butyldimethylsilyl)hydroxylamine
25g
$ 2723.00

Total 35 raw suppliers

Chemical Property of O-(tert-Butyldimethylsilyl)hydroxylamine

Chemical Property:

Vapor Pressure:1.2mmHg at 25°C
Melting Point:62-65 °C (lit.)
Refractive Index:1.419
Boiling Point:174.6 °C at 760 mmHg
PKA:4.75±0.70(Predicted)
Flash Point:40.7 °C
PSA：35.25000
Density:0.849 g/cm³
LogP:2.58220
Storage Temp.:2-8°C
Sensitive.:Moisture Sensitive
Solubility.:freely sol hexane, chloroform, and most organic solvents; insol water.
Water Solubility.:Hydrolyzes in water.
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:147.107940700
Heavy Atom Count:9
Complexity:95.7

Purity/Quality:

97% ^*data from raw suppliers

O-(tert-Butyldimethylsilyl)hydroxylamine 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)ON
Physical properties mp 62–65°C; bp 87–90°C/40 mmHg.
Uses O-(tert-Butyldimethylsilyl)hydroxylamine (tert-butyldimethylsilyl-O-hydroxylamine)is used to induce the cleavage, during solid supported synthesis of hydroxamic acids. It also finds it uses as a chemical additive and an intermediate. O-(tert-Butyldimethylsilyl)hydroxylamine (tert-butyldimethylsilyl-O-hydroxylamine) may be used to induce the cleavage, during solid supported synthesis of hydroxamic acids.

Technology Process of O-(tert-Butyldimethylsilyl)hydroxylamine

There total 1 articles about O-(tert-Butyldimethylsilyl)hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 41879-39-4
O-(tert-butyldimethylsilanyl)hydroxylamine

Guidance literature:: With hydroxylamine hydrochloride; ethylenediamine; In dichloromethane; at 20 ℃; for 72h; Inert atmosphere;
DOI:10.1002/anie.201706273