(S)-(-)-2-((1-HYDROXY-3,3-DIMETHYLBUTAN-2-YLIMINO)METHYL)-4,6-DIIODOPHENOL, 97%

Base Information

• Chemical Name: (S)-(-)-2-((1-HYDROXY-3,3-DIMETHYLBUTAN-2-YLIMINO)METHYL)-4,6-DIIODOPHENOL, 97%
• CAS No.: 477339-39-2
• Molecular Formula: C13H17I2NO2
• Molecular Weight: 473.09
• Mol file: 477339-39-2.mol

Synonyms:

Chemical Property of (S)-(-)-2-((1-HYDROXY-3,3-DIMETHYLBUTAN-2-YLIMINO)METHYL)-4,6-DIIODOPHENOL, 97%

Chemical Property:

• Vapor Pressure: 1.45E-08mmHg at 25°C
• Melting Point: 164-168 °C
• Refractive Index: 1.636
• Boiling Point: 441.3°C at 760 mmHg
• PKA: 14.68±0.10(Predicted)
• Flash Point: 220.7°C
• PSA: 52.82000
• Density: 1.88g/cm³
• LogP: 3.42730
• Storage Temp.: 2-8°C

Purity/Quality:

98%Min ^*data from raw suppliers

(S)-(?)-2-[(1-Hydroxy-3,3-dimethylbutan-2-ylimino)methyl]-4,6-diiodophenol 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36/37/38
• Safety Statements: 26

MSDS Files:

Useful:

• Uses: Useful in catalytic asymmetric sulfoxidation of alkyl aryl sulfides and in the kinetic resolution of alkyl aryl sulfoxides.

Technology Process of (S)-(-)-2-((1-HYDROXY-3,3-DIMETHYLBUTAN-2-YLIMINO)METHYL)-4,6-DIIODOPHENOL, 97%

There total 3 articles about (S)-(-)-2-((1-HYDROXY-3,3-DIMETHYLBUTAN-2-YLIMINO)METHYL)-4,6-DIIODOPHENOL, 97% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3,5-diodosalicylaldehyde (2631-77-8) + (S)-tert-leucinol (112245-13-3) → (S,E)-2-(((1-hydroxy-3,3-dimethylbutan-2-yl)imino)methyl)-4,6-diiodophenol (477339-39-2)

Guidance literature:

With sodium sulfate; In methanol; for 12h; Heating;

DOI:10.1039/b613212j

Reference yield: 86.0%

3,5-diodosalicylaldehyde (2631-77-8) + (S)-tert-leucinol (112245-13-3) → (S)-(-)-2-(N-3,5-diiodosalicylidene)amino-3,3-dimethyl-1-butanol (778625-56-2,477339-39-2)

Guidance literature:

In methanol; at 25 ℃; for 48h; Inert atmosphere;

DOI:10.1002/0471264229.os086.13

Reference yield: 70.6%

3,5-diodosalicylaldehyde (2631-77-8) + (2R)-2-amino-3,3-dimethylbutan-1-ol (3907-02-6,93684-72-1,112245-13-3,112245-09-7) → (R)-2-((1-hydroxy-3,3-dimethylbutan-2-ylimino)methyl)-4,6-diiodophenol (778625-56-2,477339-39-2)

Guidance literature:

In methanol; at 20 ℃; for 3h;

DOI:10.1021/jm101623p

upstream raw materials:

3,5-diodosalicylaldehyde

(S)-tert-leucinol

(2R)-2-amino-3,3-dimethylbutan-1-ol