(4-Ethoxy-3-formylphenyl)boronic acid

Base Information

Chemical Name:(4-Ethoxy-3-formylphenyl)boronic acid
CAS No.:480424-63-3
Molecular Formula:C9H11BO4
Molecular Weight:193.995
Hs Code.:2931900090
European Community (EC) Number:622-218-0
DSSTox Substance ID:DTXSID60584876
Wikidata:Q82476617
Mol file:480424-63-3.mol

Synonyms:480424-63-3;(4-Ethoxy-3-formylphenyl)boronic acid;3-Formyl-4-ethoxyphenylboronic acid;4-Ethoxy-3-formylphenylboronic acid;(4-Ethoxy-3-formylphenyl)boronicacid;SCHEMBL2146107;DTXSID60584876;ODRRAKCLFURNFU-UHFFFAOYSA-N;MFCD06801740;AKOS004114149;AB30217;4-Ethoxy-3-formyl-benzene boronic acid;BS-24903;CS-0174489;4-Ethoxy-3-formylphenylboronic acid, >=95%;EN300-7366446;A871984

Suppliers and Price of (4-Ethoxy-3-formylphenyl)boronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3-Formyl-4-ethoxyphenylboronicacid
250mg
$ 100.00

Sigma-Aldrich
4-Ethoxy-3-formylphenylboronic acid ≥95%
1g
$ 104.00

Crysdot
4-Ethoxy-3-formylphenylboronic acid 95+%
5g
$ 357.00

American Custom Chemicals Corporation
4-ETHOXY-3-FORMYLPHENYLBORONIC ACID 95.00%
1G
$ 222.60

Alichem
4-Ethoxy-3-formylphenylboronic acid
5g
$ 400.00

AK Scientific
3-Formyl-4-ethoxyphenylboronicacid
5g
$ 557.00

Total 17 raw suppliers

Chemical Property of (4-Ethoxy-3-formylphenyl)boronic acid

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Melting Point:175-189 °C
Refractive Index:1.531
Boiling Point:399.962°C at 760 mmHg
Flash Point:195.69°C
PSA：66.76000
Density:1.218g/cm³
LogP:-0.42240
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:194.0750390
Heavy Atom Count:14
Complexity:186

Purity/Quality:

97% ^*data from raw suppliers

3-Formyl-4-ethoxyphenylboronicacid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:C
Statements: 34
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC(=C(C=C1)OCC)C=O)(O)O

Technology Process of (4-Ethoxy-3-formylphenyl)boronic acid

There total 2 articles about (4-Ethoxy-3-formylphenyl)boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 945997-02-4
C₁₃H₁₉BrO₃

: 480424-63-3
4-ethoxy-3-formylbenzene boronic acid

Guidance literature:: C₁₃H₁₉BrO₃; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.666667h;

With triethyl borate; In diethyl ether; hexane; at -78 ℃; for 4.16667h;

With hydrogenchloride; water; In diethyl ether; hexane; at 20 ℃; for 17.5h; Heating / reflux;

Reference yield:

: 150-46-9
triethyl borate

: C₁₁H₁₅BrO₃

: 480424-63-3
4-ethoxy-3-formylbenzene boronic acid

Guidance literature:: C₁₁H₁₅BrO₃; With n-butyllithium; In hexanes; diethyl ether; at -78 ℃; for 0.666667h;

triethyl borate; In hexanes; diethyl ether; at -78 ℃; for 4.16667h;

With hydrogenchloride; water; In hexanes; diethyl ether; at -78 - 20 ℃; for 16h; Heating / reflux;

Reference yield: 96.0%

: trans-tert-butyl N-(4-aminocyclohexyl)-N-methyl-carbamate

: 480424-63-3
4-ethoxy-3-formylbenzene boronic acid

: trans-3-{[4-(tert-butoxycarbonyl-methyl-amino)-cyclohexylamino]methyl}-4-ethoxy-benzeneboronic acid

Guidance literature:: trans-tert-butyl N-(4-aminocyclohexyl)-N-methyl-carbamate; 4-ethoxy-3-formylbenzene boronic acid; With acetic acid; In tetrahydrofuran; toluene; at 20 ℃; for 2h;

With sodium tris(acetoxy)borohydride; In tetrahydrofuran; toluene; for 16h;

With water; sodium hydrogencarbonate; In tetrahydrofuran; toluene;