Methyl 6-amino-6-deoxy-beta-D-threo-hexopyranoside

Base Information

• Chemical Name: Methyl 6-amino-6-deoxy-beta-D-threo-hexopyranoside
• CAS No.: 496811-81-5
• Molecular Formula: C7H15NO5
• Molecular Weight: 193.2
• DSSTox Substance ID: DTXSID50704889
• Mol file: 496811-81-5.mol

Synonyms:496811-81-5;DTXSID50704889;AKOS015961723;AC-14722;Methyl 6-amino-6-deoxy-beta-D-threo-hexopyranoside

Chemical Property of Methyl 6-amino-6-deoxy-beta-D-threo-hexopyranoside

Chemical Property:

• Vapor Pressure: 5.81E-07mmHg at 25°C
• Refractive Index: 1.55
• Boiling Point: 369.5°Cat760mmHg
• Flash Point: 177.2°C
• PSA: 105.17000
• Density: 1.39g/cm³
• LogP: -1.90060
• XLogP3: -2.3
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 193.09502258
• Heavy Atom Count: 13
• Complexity: 167

Purity/Quality:

95% ^*data from raw suppliers

METHYL 6-AMINO-6-DEXOY-D-GLUCOPYRANOSIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1C(C(C(C(O1)CN)O)O)O
• Isomeric SMILES: CO[C@H]1[C@H](C([C@@H](C(O1)CN)O)O)O

Technology Process of Methyl 6-amino-6-deoxy-beta-D-threo-hexopyranoside

There total 54 articles about Methyl 6-amino-6-deoxy-beta-D-threo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methyl 6-azido-6-deoxy-α-D-glucopyranoside (23701-87-3) → methyl 6-amino-6-deoxy-α-D-glucopyranoside (5155-47-5,68396-86-1,68422-61-7,79695-15-1,83334-22-9,83377-36-0,104714-43-4,104714-44-5,496811-81-5)

Guidance literature:

With hydrogen; In methanol; for 18h;

DOI:10.1016/j.bmc.2011.07.019

Reference yield: 99.0%

methyl 6-azido-6-deoxy-α-D-mannopyranoside (66224-56-4) → methyl 6-amino-6-deoxy-α-D-mannopyrannoside (79695-15-1,496811-81-5)

Guidance literature:

With hydrogen; platinum(IV) oxide; In methanol; for 24h; Ambient temperature;

DOI:10.1016/0008-6215(93)84269-C

Reference yield: 91.0%

methyl 6-azido-6-deoxy-α-D-mannopyrannoside → methyl 6-amino-6-deoxy-α-D-mannopyrannoside (79695-15-1,496811-81-5)

Guidance literature:

With sodium iodide; In methanol; at 40 ℃;

DOI:10.1039/c6cc08574a

upstream raw materials:

methyl 6-O-tosyl-α-D-glucopyranoside

methyl-alpha-D-glucopyranoside

methyl 6-azido-6-deoxy-α-D-glucopyranoside

methanol

Downstream raw materials:

Ranimustine

methyl 6-deoxy-6-((2S,6S)-6-methoxy-2-(hydroxymethyl)morpholin-4-yl)-α-D-glucopyranoside

C₁₄H₂₁NO₅

C₁₄H₂₀N₂O₇

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