alpha-D-ribo-Hexofuranose,5,6-dideoxy-3-C-ethenyl-1,2-O-(1-methylethylidene)-(9CI)

Base Information

Chemical Name:alpha-D-ribo-Hexofuranose,5,6-dideoxy-3-C-ethenyl-1,2-O-(1-methylethylidene)-(9CI)
CAS No.:499120-93-3
Molecular Formula:C₁₁H₁₈O₄
Molecular Weight:214.262
Hs Code.:
Mol file:499120-93-3.mol

Synonyms:alpha-D-ribo-Hexofuranose,5,6-dideoxy-3-C-ethenyl-1,2-O-(1-methylethylidene)-(9CI)

Suppliers and Price of alpha-D-ribo-Hexofuranose,5,6-dideoxy-3-C-ethenyl-1,2-O-(1-methylethylidene)-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of alpha-D-ribo-Hexofuranose,5,6-dideoxy-3-C-ethenyl-1,2-O-(1-methylethylidene)-(9CI)

Chemical Property:

PSA：47.92000
LogP:1.18990

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of alpha-D-ribo-Hexofuranose,5,6-dideoxy-3-C-ethenyl-1,2-O-(1-methylethylidene)-(9CI)

There total 5 articles about alpha-D-ribo-Hexofuranose,5,6-dideoxy-3-C-ethenyl-1,2-O-(1-methylethylidene)-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 137344-85-5
5,6-dideoxy-3-C-ethynyl-1,2-O-isopropylidene-α-D-ribo-hexafuranose

: 499120-93-3
(2R,3R,4R,5R)-5-ethyl-4-hydroxy-2,3-isopropylidenedioxy-4-vinyltetrahydrofuran

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; for 3h; Ambient temperature;
DOI:10.1016/S0040-4020(01)96152-6

Reference yield: 83.0%

: 16749-42-1
5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hexofuranose

: 1826-67-1
vinyl magnesium bromide

: 499120-93-3
(2R,3R,4R,5R)-5-ethyl-4-hydroxy-2,3-isopropylidenedioxy-4-vinyltetrahydrofuran

Guidance literature:: 5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hexofuranose; With pyridinium chlorochromate; In dichloromethane;

vinyl magnesium bromide; In tetrahydrofuran; at -18 ℃;

Reference yield:

: 16749-42-1
5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hexofuranose

: 499120-93-3
(2R,3R,4R,5R)-5-ethyl-4-hydroxy-2,3-isopropylidenedioxy-4-vinyltetrahydrofuran

Guidance literature:: Multi-step reaction with 2 steps

1: pyridinium chlorochromate; molecular sieves 4 Angstroem / CH₂Cl₂ / 10 h / 20 °C

2: tetrahydrofuran / 1 h / -18 °C

With 4 A molecular sieve; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1246/bcsj.77.1703