(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

Base Information

Chemical Name:(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
CAS No.:55700-44-2
Molecular Formula:C₂₆H₂₈FeNP
Molecular Weight:441.336
Hs Code.:29319090
Mol file:55700-44-2.mol

Synonyms:(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE;

Suppliers and Price of (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(R)?-?(-?)?-?N,?N-?Dimethyl-?1-?[(S)?-?2-?(diphenylphosphino)?ferrocenyl]?ethylamine
5mg
$ 55.00

TCI Chemical
(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine >96.0%(HPLC)
100mg
$ 84.00

Sigma-Aldrich
(R)-(?)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine 95%
100mg
$ 71.00

Crysdot
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine 97%
1g
$ 660.00

Crysdot
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine 97%
250mg
$ 264.00

Crysdot
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine 97%
100mg
$ 165.00

Chem-Impex
(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine,96%(HPLC) 96%(HPLC)
100MG
$ 84.00

BLDpharm
(R)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine 98+%
250mg
$ 27.00

BLDpharm
(R)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine 98+%
100mg
$ 20.00

BLDpharm
(R)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine 98+%
1g
$ 75.00

Total 44 raw suppliers

Chemical Property of (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

Chemical Property:

Melting Point:141-143 °C(lit.)
Refractive Index: ">
PSA：16.83000
LogP:4.53500
Storage Temp.:under inert gas (nitrogen or Argon) at 2–8 °C
Sensitive.:Air Sensitive
Water Solubility.:Insoluble in water.

Purity/Quality:

95% ^*data from raw suppliers

(R)?-?(-?)?-?N,?N-?Dimethyl-?1-?[(S)?-?2-?(diphenylphosphino)?ferrocenyl]?ethylamine ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/21/22-36/37/38
Safety Statements: 26-36-36/37/38

MSDS Files:: SDS file from LookChem

Useful:

Uses Ligand used in the enantioselective vinylation of aldehydes.

Technology Process of (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

There total 1 articles about (R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 83560-65-0
[2-(α-(dimethylamino)ethyl)-1,1'-ferrocenediyl]phenylphosphine

: 591-51-5
phenyllithium

: 55700-44-2,60816-98-0,137695-36-4,105088-01-5,74311-54-9,55650-58-3
N,N-dimethyl-(2-(diphenylphosphino)ferrocenyl)-1-(methyl-1-methylamine)

: 85150-25-0,103948-69-2
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)

Guidance literature:: With water; In diethyl ether; under N2 atm. to etheral soln. phenyllithium at -78°C soln. (Me2NC(CH3)HC5H3)Fe(C5H4)P(C6H5) in ether added dropwise and stirred for 5 min at -78°C before it warmed slowly to room temp., water added; etheral layer separated, dried over anhyd. MgSO4, volume reduced, residue redissolved in chloroform and chromed. with hexane/ether 50/50 as eluent, then with Et2O, solvent removed, product recrystd. at -20°C from hexane; elem. anal.;

Reference yield: 82.0%

: (2-methylallyl)palladium-chloride dimer

: 55700-44-2,60816-98-0,137695-36-4,105088-01-5,74311-54-9,55650-58-3
N,N-dimethyl-(2-(diphenylphosphino)ferrocenyl)-1-(methyl-1-methylamine)

: 2923-28-6
silver trifluoromethanesulfonate

: 193815-95-1
[Pd(η(3)-2-Me-C3H4)Pd((C5H5)Fe(C5H3(CH(Me)NMe2)P(C6H5)2))]OSO2CF3

Guidance literature:: In methanol; dichloromethane; N2-atmosphere; stirring (dark, 1 h); filtering, evapn., pptn. on hexane and Et2O addn., recrystn. (CH2Cl2 / Et2O); elem. anal.;
DOI:10.1021/om9610354

Reference yield: 58.0%

: chloromethyl(1,5-cyclooctadiene)palladium(II)

: 55700-44-2,60816-98-0,137695-36-4,105088-01-5,74311-54-9,55650-58-3
N,N-dimethyl-(2-(diphenylphosphino)ferrocenyl)-1-(methyl-1-methylamine)

: 214825-64-6
PdClCH₃(2-(1-dimethylaminoethyl)-1-diphenylphosphinoferrocene)

Guidance literature:: In toluene; N2-atmosphere; stirring (room temp., 16 h); evapn., washing (hexane), filtering; elem. anal.;
DOI:10.1021/om980312z