Polyoxirane-2,3-dicarboxylic acid

Base Information

• Chemical Name: Polyoxirane-2,3-dicarboxylic acid
• CAS No.: 51274-37-4
• Molecular Formula: (C4H4O5)n
• Molecular Weight: 132.07
• Mol file: 51274-37-4.mol

Synonyms:Polyoxirane-2,3-dicarboxylic acid

Chemical Property of Polyoxirane-2,3-dicarboxylic acid

Chemical Property:

• PSA: 93.06000
• LogP: 0.68930
• Solubility.: H2O: soluble

Purity/Quality:

≥90.0%, ^*data from raw suppliers

Polyepoxysuccinic acid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Scale inhibitor

Technology Process of Polyoxirane-2,3-dicarboxylic acid

There total 31 articles about Polyoxirane-2,3-dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

trans-2,3-bis(ethoxycarbonyl)oxirane (74243-85-9) → (2R,3R)-oxirane-2,3-dicarboxylic acid (17015-08-6,51274-37-4)

Guidance literature:

With potassium hydroxide; In ethanol; for 3h; Ambient temperature;

DOI:10.1021/jo00168a038

Reference yield: 60.0%

(2E)-but-2-enedioic acid (110-17-8,26099-09-2) → 2,3-oxiranedicarboxylic acid (3272-11-5,51274-37-4)

Guidance literature:

(2E)-but-2-enedioic acid; With sodium tungstate; sodium hydroxide; In water; at 70 ℃;

With dihydrogen peroxide; sodium hydroxide; In water; at 65 - 80 ℃; for 4h;

DOI:10.1016/j.cclet.2013.05.002

Reference yield: 60.0%

(2E)-but-2-enedioic acid (110-17-8,26099-09-2) → (2R,3R)-oxirane-2,3-dicarboxylic acid (17015-08-6,51274-37-4)

Guidance literature:

With dihydrogen peroxide; sodium tungstate;

upstream raw materials:

(+/-)-2-chloro-3-hydroxy-succinic acid

β-bromo-dl-malic acid

maleic acid

(2E)-but-2-enedioic acid

Downstream raw materials:

(2R,3S)-dimethyl oxirane-2,3-dicarboxylate

meso-epoxy-succinyl chloride

N-(DL-α-Methyl-benzyl)-threo-β-hydroxy-DL-asparaginsaeure

D-(-)-Benzyl-erythro-β-hydroxy-asparaginsaeure

Refernces

• 1、 Zwirchmayr, Nele Sophie,Hosoya, Takashi,Henniges, Ute,Gille, Lars,Bacher, Markus,Furtmüller, Paul,Rosenau, Thomas. "Degradation of the Cellulosic Key Chromophore 5,8-Dihydroxy-[1,4]-naphthoquinone by Hydrogen Peroxide under Alkaline Conditions". . p. 11558 - 11565. Retrieved 2017/11/10.
• 2、 -. "2, 3-Butanediamide Epoxide Compound and Preparation Method and Use Thereof". Paragraph 0159. . Retrieved 2016/05/19.