BORON TRIFLUORIDE PIPERIDINE COMPLEX

Base Information

• Chemical Name: BORON TRIFLUORIDE PIPERIDINE COMPLEX
• CAS No.: 592-39-2
• Molecular Formula: C5H11BF3N
• Molecular Weight: 152.955
• Mol file: 592-39-2.mol

Synonyms:PIPERIDINIUM TRIFLUOROBORATE;BORON TRIFLUORIDE PIPERIDINE COMPLEX;Boron,trifluoro(piperidine)-,(T-4)-;Piperidine,compd.withtrifluoroborane(1:1);trifluoro(piperidine)-,(T-4)-Boron;trifluoro(piperidine)boron;(T-4)-trifluoro(piperidine)-Boron;Piperidine, compd. with trifluoroborane

Chemical Property of BORON TRIFLUORIDE PIPERIDINE COMPLEX

Chemical Property:

• Vapor Pressure: 28.3mmHg at 25°C
• Melting Point: 73°C
• Refractive Index: ">
• Boiling Point: 106.4°Cat760mmHg
• Flash Point: 4.4°C
• PSA: 12.03000
• Density: g/cm³
• LogP: 1.96850

Purity/Quality:

99.9% ^*data from raw suppliers

BORON(T-4)-TRIFLUORO(PIPERIDINE) 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BORON TRIFLUORIDE PIPERIDINE COMPLEX

There total 2 articles about BORON TRIFLUORIDE PIPERIDINE COMPLEX which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

piperidine (110-89-4) + boron trifluoride diethyl etherate (109-63-7) → trifluoro(piperidine-ium-yl)borate (592-39-2)

Guidance literature:

In dichloromethane; at 0 ℃; for 1.5h; Inert atmosphere;

DOI:10.1021/jacs.5b10299

Reference yield:

piperazine (110-85-0) + trifluoroborane diethyl ether (109-63-7) → trifluoro(piperidine-ium-yl)borate (592-39-2)

Guidance literature:

In neat (no solvent); 1.2 equiv. of borane added to 1 equiv. of dry amine at room temp. under anhyd. conditions; borane excess evapd. to result a viscous yellow liquid;

DOI:10.1021/ic000890j

upstream raw materials:

piperazine

trifluoroborane diethyl ether

piperidine

boron trifluoride diethyl etherate