.beta.-D-Glucopyranose, 1,1-dithiobis1-deoxy-, octaacetate

Base Information

Chemical Name:.beta.-D-Glucopyranose, 1,1-dithiobis1-deoxy-, octaacetate
CAS No.:5207-08-9
Molecular Formula:C28H38O18S2
Molecular Weight:726.731
Hs Code.:
Mol file:5207-08-9.mol

Synonyms:.beta.-D-Glucopyranose, 1,1-dithiobis1-deoxy-, octaacetate

Suppliers and Price of .beta.-D-Glucopyranose, 1,1-dithiobis1-deoxy-, octaacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of .beta.-D-Glucopyranose, 1,1-dithiobis1-deoxy-, octaacetate

Chemical Property:

PSA：279.46000
LogP:0.53400

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of .beta.-D-Glucopyranose, 1,1-dithiobis1-deoxy-, octaacetate

There total 6 articles about .beta.-D-Glucopyranose, 1,1-dithiobis1-deoxy-, octaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 19879-84-6
tetraacetyl thioglucose

: [(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

: (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-((2'-amino-[1,1'-biphenyl]-2-yl)thio)tetrahydro-2H-pyran-3,4,5-triyltriacetate

: 86-74-8,105184-46-1,97960-57-1
9H-carbazole

: 5207-08-9
bis(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)disulfide

Guidance literature:: With triethylamine; In tetrahydrofuran; water; at 25 ℃; for 1h; Sealed tube; Schlenk technique; Inert atmosphere;
DOI:10.1002/asia.201701415

Reference yield:

: 19879-84-6
tetraacetyl thioglucose

: 52485-06-0
3,4,6-tri-O-acetyl-D-glucal

: 108-24-7
acetic anhydride

: 1356155-30-0
3,4,6-tri-O-acetyl-1,5-anhydro-2-thio-2-S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-D-altritol

: 5207-08-9
bis(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)disulfide

: 6806-56-0,13639-50-4,51898-27-2,62860-10-0,63783-77-7,92217-67-9,92217-68-0,130796-15-5
O²,O³,O⁴,O⁶,S-Pentaacetyl-1-thio-β-D-glucopyranose

Guidance literature:: tetraacetyl thioglucose; 3,4,6-tri-O-acetyl-D-glucal; With 2,2-dimethoxy-2-phenylacetophenone; In ethanol; dichloromethane; at 20 ℃; for 1h; UV-irradiation;

acetic anhydride; With pyridine; at 20 ℃; for 2h; optical yield given as %de; regioselective reaction;
DOI:10.1016/j.tetlet.2011.11.140

Reference yield:

: 19879-84-6
tetraacetyl thioglucose

: 6586-65-8
3,4,6-tri-O-acetyl-D-galactal

: 108-24-7
acetic anhydride

: 1356155-31-1
C₂₆H₃₆O₁₆S

: 5207-08-9
bis(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)disulfide

: 6806-56-0,13639-50-4,51898-27-2,62860-10-0,63783-77-7,92217-67-9,92217-68-0,130796-15-5
O²,O³,O⁴,O⁶,S-Pentaacetyl-1-thio-β-D-glucopyranose

Guidance literature:: tetraacetyl thioglucose; 3,4,6-tri-O-acetyl-D-galactal; With 2,2-dimethoxy-2-phenylacetophenone; In ethanol; dichloromethane; at 20 ℃; for 1h; UV-irradiation;

acetic anhydride; With pyridine; at 20 ℃; for 2h; optical yield given as %de; regioselective reaction;
DOI:10.1016/j.tetlet.2011.11.140