4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl

Base Information

Chemical Name:4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl
CAS No.:5487-93-4
Molecular Formula:C22H28B2O4
Molecular Weight:378.084
Hs Code.:2934999090
European Community (EC) Number:693-558-5
DSSTox Substance ID:DTXSID20581740
Nikkaji Number:J673.124D
Wikidata:Q82472970
Mol file:5487-93-4.mol

Synonyms:5487-93-4;4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl;4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-1,1'-biphenyl;4,4'-Biphenyldiboronic Acid Bis(neopentyl Glycol) Ester;2-[4-[4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl]phenyl]-5,5-dimethyl-1,3,2-dioxaborinane;4,4'-Biphenyldiboronic acid, neopentyl glycol ester;4-4'_Biphenyldiboronic acid bis (neopentyl glycol) ester;Biphenyl-4,4'-diboronic acid bis(neopentyl glycol) ester;4,4'-Biphenyldiboronic acid bis(neopentyl) ester;4,4-Biphenyldiboronic acid bis(neopentyl glycol)ester;SCHEMBL4257326;DTXSID20581740;NJXUWONHNYJPMY-UHFFFAOYSA-N;4,4-BIPHENYLDIBORONIC ACID BIS(NEOPENTYL GLYCOL) ESTER;MFCD01318103;AKOS015842266;AS-3292;B3151;4,4-Biphenyldiboronic acid bis(neopentylglycol);T71046;4,4-Biphenyldiboronic acid, neopentyl glycol ester;A923656;4,4'-Biphenyldiboronic acid bis(neopentyl) ester, 97%;4,4-BIPHENYLDIBORONICACIDBIS(NEOPENTYLGLYCOL)ESTER;2,2'-([1,1'-Biphenyl]-4,4'-diyl)bis(5,5-dimethyl-1,3,2-dioxaborinane);2-[4'-(5,5-DIMETHYL-1,3,2-DIOXABORINAN-2-YL)-[1,1'-BIPHENYL]-4-YL]-5,5-DIMETHYL-1,3,2-DIOXABORINANE

Suppliers and Price of 4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4,4''-BiphenyldiboronicAcidbis(NeopentylGlycol)Ester
100mg
$ 60.00

TRC
4,4''-BiphenyldiboronicAcidbis(NeopentylGlycol)Ester
500mg
$ 90.00

TCI Chemical
4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl >98.0%(GC)(T)
1g
$ 222.00

Sigma-Aldrich
4,4′-Biphenyldiboronic acid bis(neopentyl) ester 97%
1g
$ 115.00

Chem-Impex
4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl,98%(GC) 98%(GC)
1G
$ 209.44

Biosynth Carbosynth
4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl
5 g
$ 448.00

Biosynth Carbosynth
4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl
2 g
$ 224.00

Biosynth Carbosynth
4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl
500 mg
$ 75.00

Biosynth Carbosynth
4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl
250 mg
$ 45.00

Biosynth Carbosynth
4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl
1 g
$ 132.00

Total 20 raw suppliers

Chemical Property of 4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl

Chemical Property:

Melting Point:244-246°C
Boiling Point:519.3oC at 760 mmHg
Flash Point:267.8oC
PSA：36.92000
Density:1.09g/cm3
LogP:2.89000
Water Solubility.:Insoluble in water
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:378.2173697
Heavy Atom Count:28
Complexity:445

Purity/Quality:

98% ^*data from raw suppliers

4,4''-BiphenyldiboronicAcidbis(NeopentylGlycol)Ester ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:N
Statements: 50/53
Safety Statements: 22-24/25-61-60

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OCC(CO1)(C)C)C2=CC=C(C=C2)C3=CC=C(C=C3)B4OCC(CO4)(C)C

Technology Process of 4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl

There total 5 articles about 4,4'-Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 92-86-4
4-(4-bromophenyl)bromobenzene

: 5487-93-4
4,4'-biphenyldiboronic acid bis(neopentyl glycol) cyclic ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 2 h / -78 °C

1.2: 5 h / -78 - 0 °C

2.1: toluene / 36 h / Reflux; Dean-Stark

With n-butyllithium; In tetrahydrofuran; hexane; toluene;
DOI:10.1002/anie.201407387

Reference yield:

: 4151-80-8
4,4'-biphenyldiboronic acid

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 5487-93-4
4,4'-biphenyldiboronic acid bis(neopentyl glycol) cyclic ester

Guidance literature:: In benzene;
DOI:10.1039/j39660000566

Reference yield:

: 624-38-4,1032416-46-8
para-diiodobenzene

: 5487-93-4
4,4'-biphenyldiboronic acid bis(neopentyl glycol) cyclic ester

Guidance literature:: Multi-step reaction with 2 steps

1: (i) (UV-irradiation), BBr₃, Ag, (ii) aq. NaOH

2: benzene

In benzene;
DOI:10.1039/j39660000566