Technology Process of Benzenamine, 2-ethyl-4-[(trimethylsilyl)ethynyl]- (9CI)
There total 1 articles about Benzenamine, 2-ethyl-4-[(trimethylsilyl)ethynyl]- (9CI) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine;
at 20 ℃;
DOI:10.1016/S0040-4020(02)01409-6
- Guidance literature:
-
2-ethyl-4-(trimethylsilylethynyl)aniline;
With
tert.-butylnitrite; boron trifluoride diethyl etherate;
In
diethyl ether;
at -20 - 5 ℃;
With
iodine; sodium iodide;
In
acetonitrile;
at 20 ℃;
for 1h;
DOI:10.1016/S0040-4020(02)01409-6
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: BF3*Et2O; t-BuONO / diethyl ether / -20 - 5 °C
1.2: 86 percent / NaI; I2 / acetonitrile / 1 h / 20 °C
2.1: K2CO3 / methanol; CH2Cl2
With
tert.-butylnitrite; boron trifluoride diethyl etherate; potassium carbonate;
In
methanol; diethyl ether; dichloromethane;
DOI:10.1016/S0040-4020(02)01409-6
