1,2,4,6-Tetraphenylpyridinium tetrafluoroborate

Base Information

• Chemical Name: 1,2,4,6-Tetraphenylpyridinium tetrafluoroborate
• CAS No.: 59834-94-5
• Molecular Formula: C29H22B4F16N-3
• Molecular Weight: 471.305
• European Community (EC) Number: 635-811-4
• DSSTox Substance ID: DTXSID20506175
• Mol file: 59834-94-5.mol

Synonyms:1,2,4,6-TETRAPHENYLPYRIDINIUM TETRAFLUOROBORATE;59834-94-5;1,2,4,6-tetraphenylpyridin-1-ium;tetrafluoroborate;1,2,4,6-Tetraphenylpyridin-1-ium tetrafluoroborate;SCHEMBL1501554;DTXSID20506175;WJMVXJXAHPJPPF-UHFFFAOYSA-N;AKOS024434512;FT-0606241

Chemical Property of 1,2,4,6-Tetraphenylpyridinium tetrafluoroborate

Chemical Property:

• Melting Point: 241-242 °C (decomp)
• PSA: 3.88000
• LogP: 8.26430
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 471.1781425
• Heavy Atom Count: 35
• Complexity: 482

Purity/Quality:

98%Min ^*data from raw suppliers

N-Phenyl-2,4,6-triphenylPyridiniumTetrafluoroborate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [B-](F)(F)(F)F.C1=CC=C(C=C1)C2=CC(=[N+](C(=C2)C3=CC=CC=C3)C4=CC=CC=C4)C5=CC=CC=C5

Technology Process of 1,2,4,6-Tetraphenylpyridinium tetrafluoroborate

There total 3 articles about 1,2,4,6-Tetraphenylpyridinium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2,4,6-triphenylpyrylium tetrafluoroborate (448-61-3) + aniline (62-53-3) → 1-phenyl-2,4,6-triphenylpyridin-1-ium tetrafluoroborate (59834-94-5)

Guidance literature:

In ethanol; for 15h; Reflux;

DOI:10.1021/ja902420u

Reference yield: 87.0%

→ 1-phenyl-2,4,6-triphenylpyridin-1-ium tetrafluoroborate (59834-94-5)

Guidance literature:

Reference yield:

2,4,6-triphenylpyrylium tetrafluoroborate (448-61-3) + aniline (62-53-3) → 1,3,5-Triphenyl-2-pentene-1,5-dione (76162-49-7) + 1-phenyl-2,4,6-triphenylpyridin-1-ium tetrafluoroborate (59834-94-5)

Guidance literature:

With triethylamine; In chloroform-d1;

upstream raw materials:

2,4,6-triphenylpyrylium tetrafluoroborate

aniline

Downstream raw materials:

1,3,5-Triphenyl-2-benzoyl-4-bromopyrrole

1,3,5-Triphenyl-2-benzoyl-4-acetylpyrrole

1,3,5-Triphenyl-2-benzoyl-4-nitropyrrole

9-Phenyl-benzo[1,2]quinolizino[3,4,5,6-fed]phenanthridinylium benzenesulfonate