76162-49-7Relevant articles and documents
Regiocontrolled synthesis of 2,4,6-triarylpyridines from methyl ketones, electron-deficient acetylenes and ammonium acetate
Shabalin, Dmitrii A.,Dvorko, Marina Yu.,Schmidt, Elena Yu.,Trofimov, Boris A.
supporting information, p. 2703 - 2715 (2021/04/07)
A novel one-pot two-step approach for the synthesis of 2,4,6-triarylpyridinesvia t-BuOK/DMSO-promotedC-vinylation of a variety of methyl ketones with electron-deficient acetylenes (alkynones) followed by a cyclization of thein situgenerated unsaturated 1,5-dicarbonyl species with ammonium acetate has been developed. This approach possesses competitive advantages such as high regioselectivity, available starting materials and the absence of transition-metal catalysts, oxidants and undesirable byproducts. A wide synthetic utility of the developed approach was demonstrated by the synthesis of trisubstituted, tetrasubstituted and fused pyridines.
Free Radicals: XXVI. Reaction of 2,4,6-Triphenylpyranyl Radical with Oxygen
Tanaseichuk, B. S.,Pryanichnikova, M. K.,Tikhonova, L. G.
, p. 442 - 444 (2007/10/03)
Triphenylpyranyl radical reacts with oxygen to give 1,3,5-tiphenyl-2-pentene-1,5-dione, 3-phenoxymethyl-2,5-diphenylfuran, and 5-phenoxymethyl-2,4-diphenylfuran.
REACTION OF 2,4,6-TRIPHENYL-4H-PYRAN WITH THE VILSMEIER REAGENT
Koblik, A. V.,Suzdalev, K. F.
, p. 1206 - 1207 (2007/10/02)
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