TRI-N-BUTYLTIN DEUTERIDE

Base Information

• Chemical Name: TRI-N-BUTYLTIN DEUTERIDE
• CAS No.: 6180-99-0
• Molecular Formula: C12H27DSn
• Molecular Weight: 292.056
• Hs Code.: 28459000
• European Community (EC) Number: 621-232-4
• DSSTox Substance ID: DTXSID70369858
• Wikidata: Q82157141
• Mol file: 6180-99-0.mol

Synonyms:TRI-N-BUTYLTIN DEUTERIDE;TRIBUTYLTIN DEUTERIDE;Deuterotri-n-butylstannane;Tributyldeuteriostannane;Tributylhydro-d-tin;Tributyl-stannane-d;Tributylstannyl Deuteride;Stannane-d, tributyl-

Chemical Property of TRI-N-BUTYLTIN DEUTERIDE

Chemical Property:

• Vapor Pressure: 0.00606mmHg at 25°C
• Refractive Index: n20/D 1.472(lit.)
• Boiling Point: 65 °C (0.6 mmHg)
• Flash Point: 104 °F
• PSA: 0.00000
• Density: 1.082 g/mL at 25 °C(lit.)
• LogP: 4.61380
• Storage Temp.: Refrigerator (+4°C)
• Sensitive.: Air & Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 293.127580
• Heavy Atom Count: 13
• Complexity: 72.1

Purity/Quality:

99% ^*data from raw suppliers

Tri-n-butyltin Deuteride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 35-36/37/39-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC[SnH](CCCC)CCCC
• Isomeric SMILES: [2H][Sn](CCCC)(CCCC)CCCC
• Uses: Dangerous for the environment

Technology Process of TRI-N-BUTYLTIN DEUTERIDE

There total 1 articles about TRI-N-BUTYLTIN DEUTERIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenylsilyl deuteride (18536-60-2) + tributyltin methoxide (1067-52-3) + HSiPh3 (789-25-3) → tri-n-butyl-tin hydride (688-73-3) + tributyltin deuteride (6180-99-0)

Guidance literature:

In toluene; byproducts: (C6H5)3SiOCH3;

DOI:10.1016/S0022-328X(00)82633-9

Reference yield: 99.0%

tributyltin deuteride (6180-99-0) + 2,2,11,11-tetramethyl-3,3,10,10-tetraphenyl-4,9-dioxa-3,10-disiladodec-6-yne (158141-90-3) → [3-2H]-bis-1,4-t-butyldiphenylsiloxy-2-iodo-but-2-ene (256431-45-5)

Guidance literature:

tributyltin deuteride; 2,2,11,11-tetramethyl-3,3,10,10-tetraphenyl-4,9-dioxa-3,10-disiladodec-6-yne; With bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; for 0.166667h;

With iodine; In diethyl ether; at 20 ℃;

DOI:10.1016/S0040-4039(99)01769-4

Reference yield: 95.0%

1-Phenylcyclohexene (771-98-2) + tributyltin deuteride (6180-99-0) → (C4H9)3SnCHC(2)HC6H5(CH2)4

Guidance literature:

under 10 kbar;

DOI:10.1039/c39800001004

upstream raw materials:

triphenylsilyl deuteride

tributyltin methoxide

HSiPh₃

Downstream raw materials:

1-deuterobutane

tributylstannyl radical

[3-2H]-bis-1,4-t-butyldiphenylsiloxy-2-iodo-but-2-ene

tributyltin bromide