Boric acid-d3

Base Information

• Chemical Name: Boric acid-d3
• CAS No.: 14149-58-7
• Molecular Formula: BD3 O3
• Molecular Weight: 64.8092
• Hs Code.: 2845901000
• European Community (EC) Number: 689-532-8
• DSSTox Substance ID: DTXSID00583601
• Nikkaji Number: J2.296.644H
• Wikidata: Q82475193
• Mol file: 14149-58-7.mol

Synonyms:Boric acid-d3;14149-58-7;trideuterio borate;Boric acid (D3BO3) (8CI,9CI);(~2~H_3_)Boric acid;Boric acid-d3, 98 atom % D;DTXSID00583601;MFCD00075279;J-007506

Chemical Property of Boric acid-d3

Chemical Property:

• Refractive Index: 1.385
• PSA: 60.69000
• Density: 1.508g/cm³
• LogP: -2.05180
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 65.0363544
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98% ^*data from raw suppliers

Boric acid-d3 98 atom % D ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,T
• Statements: 36/37/38-62-63-61-60
• Safety Statements: 22-26-36/37/39-45-53

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(O)(O)O
• Isomeric SMILES: [2H]OB(O[2H])O[2H]

Technology Process of Boric acid-d3

There total 23 articles about Boric acid-d3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(PO3BH3)(3-) → (PO3(2)H)(2-) (17382-86-4) + orthoboric acid-D3 (14149-58-7)

Guidance literature:

With water; In water-d2; 60°C; (1)H, (31)P, NMR monitoring; Kinetics;

DOI:10.1021/ja9540280

Reference yield:

4,4-bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b’]dithiophene-2,6-diyl-MIDA-boronate → C5H7(2)H2NO4 + C25H36(2)H2S2 + orthoboric acid-D3 (14149-58-7)

Guidance literature:

With water-d2; hydrogen chloride; In tetrahydrofuran-d8; diethyl ether; at 23 ℃; for 24h; Time;

DOI:10.1021/jacs.6b07666

Reference yield:

trimethylamine-borane (75-22-9) + water-d2 (7789-20-0) → trimethylamine; deuteronated form (16962-53-1) + orthoboric acid-D3 (14149-58-7)

Guidance literature:

With sulfuric acid-d2; In tetrachloromethane; water-d2; byproducts: HD; 0.1 M (CH3)3NBH3 in CCl4 and 2.5 M D2SO4 in D2O; 23°C; detn. by FTIR; Kinetics;

DOI:10.1021/j100153a077

upstream raw materials:

water-d2

boric acid

trimethylamine-borane

boron nitride

Downstream raw materials:

metaboric acid

metaboric acid

Refernces

• 1、 Kitano, Tsuyoshi,Sohrin, Yoshiki,Hata, Yasuo,Mukai, Hiroshi,Wada, Hiroki,Ueda, Kazumasa. "Highly selective extraction of Cu(II) and Zn(II) using [B(3-iPrpz) 4]- (iPrpz=isopropylpyrazolyl)". . p. 283 - 289. Retrieved 2004.
• 2、 Li, Hong,Hardin, Charles,Shaw, Barbara Ramsay. "Hydrolysis of thymidine boranomonophosphate and stepwise deuterium substitution of the borane hydrogens. 31P and 11B NMR studies". . p. 6606 - 6614. Retrieved 2007/10/03.