Diphenylphosphinoferrocene

Base Information

• Chemical Name: Diphenylphosphinoferrocene
• CAS No.: 12098-17-8
• Molecular Formula: C22H19 Fe P
• Molecular Weight: 370.214
• Mol file: 12098-17-8.mol

Synonyms:Iron,cyclopentadienyl[(diphenylphosphino)cyclopentadienyl]- (7CI); Phosphine,ferrocenyldiphenyl- (8CI); Phosphine, cyclopentadienyldiphenyl-,cyclopentadienyliron deriv; 1-(Diphenylphosphino)ferrocene;Diphenylferrocenylphosphine; Diphenylphosphinoferrocene;Ferrocenyldiphenylphosphine

Chemical Property of Diphenylphosphinoferrocene

Chemical Property:

• Melting Point: 122-124 °C(Solv: heptane (142-82-5))
• PSA: 13.59000
• LogP: 3.32500

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diphenylphosphinoferrocene

There total 13 articles about Diphenylphosphinoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

ferrocene (102-54-5,55404-68-7) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → (diphenylphosphin)ferrocene (12098-17-8)

Guidance literature:

With aluminum (III) chloride; In hexane; at 0 ℃; for 2h; Temperature; Inert atmosphere;

Reference yield: 72.0%

iodobenzene (591-50-4) + ferrocenylphosphane (83528-85-2) → (diphenylphosphin)ferrocene (12098-17-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tripotassium phosphate "n" hydrate; In toluene; at 110 ℃; Reagent/catalyst; Solvent;

DOI:10.1021/om5002827

Reference yield: 68.0%

1'-dimethylvinylsilyl-1-bromoferrocene (1006375-15-0) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → (diphenylphosphin)ferrocene (12098-17-8) + 1'-dimethylvinylsilyl-1-(diphenylphosphanyl)ferrocene (1006375-13-8)

Guidance literature:

With BuLi; In tetrahydrofuran; hexane; (Ar); soln. of BuLi in hexane was added to soln. of Fe complex in THF at-78°C; stirred at -78°C for 15 min; Ph2PCl was added drop wise; stirred at -78°C for 15 min and at room temp. for 90 min; satd. aq. NaHCO3 added; stirred for 30 min; dild. with Et2O; org. layer septd.; washed (brine); dried (MgSO4); concd. (vac.); chromd. (silica gel, hexane; hexane/Et2O, 1/9); evapd.;

DOI:10.1016/j.jorganchem.2007.10.056

upstream raw materials:

ferrocene

chloro-diphenylphosphine

phenyllithium

lithiumferrocene