1'-dimethylvinylsilyl-1-(diphenylphosphanyl)ferrocene

Base Information

• Chemical Name: 1'-dimethylvinylsilyl-1-(diphenylphosphanyl)ferrocene
• CAS No.: 1006375-13-8
• Molecular Formula: C₂₆H₂₇FePSi
• Molecular Weight: 454.407
• Mol file: 1006375-13-8.mol

Synonyms:

Chemical Property of 1'-dimethylvinylsilyl-1-(diphenylphosphanyl)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1'-dimethylvinylsilyl-1-(diphenylphosphanyl)ferrocene

There total 1 articles about 1'-dimethylvinylsilyl-1-(diphenylphosphanyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

1'-dimethylvinylsilyl-1-bromoferrocene (1006375-15-0) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → (diphenylphosphin)ferrocene (12098-17-8) + 1'-dimethylvinylsilyl-1-(diphenylphosphanyl)ferrocene (1006375-13-8)

Guidance literature:

With BuLi; In tetrahydrofuran; hexane; (Ar); soln. of BuLi in hexane was added to soln. of Fe complex in THF at-78°C; stirred at -78°C for 15 min; Ph2PCl was added drop wise; stirred at -78°C for 15 min and at room temp. for 90 min; satd. aq. NaHCO3 added; stirred for 30 min; dild. with Et2O; org. layer septd.; washed (brine); dried (MgSO4); concd. (vac.); chromd. (silica gel, hexane; hexane/Et2O, 1/9); evapd.;

DOI:10.1016/j.jorganchem.2007.10.056

Reference yield: 71.0%

diiron nonacarbonyl (15321-51-4) + 1'-dimethylvinylsilyl-1-(diphenylphosphanyl)ferrocene (1006375-13-8) → tetracarbonyl-[1-(diphenylphosphanyl-κP)-1'-(dimethylvinylsilyl)ferrocene]iron(0) (1006375-18-3)

Guidance literature:

In toluene; (Ar); mixt. of Fe2(CO)9 and Fe-PPh2 complex in toluene was refluxed for 1 h; cooled to room temp.; evapd.; chromd. (silica gel, hexane/Et2O, 5/1); evapd.;

DOI:10.1016/j.jorganchem.2007.10.056

upstream raw materials:

1'-dimethylvinylsilyl-1-bromoferrocene

chloro-diphenylphosphine

Downstream raw materials:

tetracarbonyl-[1-(diphenylphosphanyl-κP)-1'-(dimethylvinylsilyl)ferrocene]iron(0)