TRIETHYL METHANETRICARBOXYLATE SODIUM

Base Information

• Chemical Name: TRIETHYL METHANETRICARBOXYLATE SODIUM
• CAS No.: 68922-87-2
• Molecular Formula: C10H15NaO6
• Molecular Weight: 254.215
• Mol file: 68922-87-2.mol

Synonyms:TRIETHYL METHANETRICARBOXYLATE SODIUM;Methanetricarboxylic Acid Triethyl Ester Sodium;Sodium Triethyl Methanetricarboxylate;Triethyl Sodium Methanetricarboxylate

Chemical Property of TRIETHYL METHANETRICARBOXYLATE SODIUM

Chemical Property:

• Vapor Pressure: 0.00358mmHg at 25°C
• Melting Point: 196-200 °C(lit.)
• Boiling Point: 281.3°C at 760 mmHg
• Flash Point: 118.3°C
• PSA: 78.90000
• LogP: 0.38370
• Solubility.: Water

Purity/Quality:

98%,99%, ^*data from raw suppliers

TriethylSodiumMethanetricarboxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Triethyl Sodium Methanetricarboxylate (cas# 68922-87-2) is a compound useful in organic synthesis.

Technology Process of TRIETHYL METHANETRICARBOXYLATE SODIUM

There total 1 articles about TRIETHYL METHANETRICARBOXYLATE SODIUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

methanetricarboxylic acid triethyl ester (6279-86-3) → sodium 1,3-diethoxy-2-(ethoxycarbonyl)-1,3-dioxopropan-2-ide (68922-87-2)

Guidance literature:

With sodium ethanolate; In diethyl ether; ethanol; Cooling with ice; Inert atmosphere;

DOI:10.1021/ja902478p

Reference yield: 92.0%

1-bromo-butane (109-65-9) + sodium 1,3-diethoxy-2-(ethoxycarbonyl)-1,3-dioxopropan-2-ide (68922-87-2) → 1,1,1-Tris(ethoxycarbonyl)pentane (3272-32-0)

Guidance literature:

In tetrahydrofuran; N,N-dimethyl-formamide; toluene; benzene; at 85 ℃; for 6h;

Reference yield: 88.0%

4-(benzyloxy)but-2-yn-1-yl4-methylbenzenesulfonate (209348-46-9) + sodium 1,3-diethoxy-2-(ethoxycarbonyl)-1,3-dioxopropan-2-ide (68922-87-2) → ethyl 6-benzyloxy-2,2-diethoxycarbonyl-hex-4-ynoate (1289154-37-5)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; In toluene; at 80 ℃; for 2h; Inert atmosphere;

DOI:10.1039/c0cc05646d

upstream raw materials:

methanetricarboxylic acid triethyl ester

Downstream raw materials:

1,1,1-Tris(ethoxycarbonyl)pentane

triethyl 3-bromopropane-1,1,1-tricarboxylate

3-[3,5-Bis-(2,2,2-tris-ethoxycarbonyl-ethyl)-phenyl]-2,2-bis-ethoxycarbonyl-propionic acid ethyl ester

Tris(ethoxycarbonyl)-9-fluorenylmethane