4-(4-Bromophenoxy)benzaldehyde

Base Information

• Chemical Name: 4-(4-Bromophenoxy)benzaldehyde
• CAS No.: 69240-56-8
• Molecular Formula: C13H9BrO2
• Molecular Weight: 277.117
• Hs Code.: 2913000090
• European Community (EC) Number: 622-123-4
• DSSTox Substance ID: DTXSID80442863
• Nikkaji Number: J3.114.873A
• Wikidata: Q82260417
• Mol file: 69240-56-8.mol

Synonyms:4-(4-Bromophenoxy)benzaldehyde;69240-56-8;4-(4-Bromo-phenoxy)benzaldehyde;SCHEMBL260494;4-(4-bromophenoxy) benzaldehyde;DTXSID80442863;WMDDJOBNAOVSLP-UHFFFAOYSA-N;MFCD08276811;AKOS000260023;4-(4-Bromophenoxy)benzaldehyde, 97%;AS-8717;B4900;CS-0157440;FT-0749086;T71237

Chemical Property of 4-(4-Bromophenoxy)benzaldehyde

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 69-73 °C
• Refractive Index: 1.633
• Boiling Point: 364.712°C at 760 mmHg
• Flash Point: 174.372°C
• PSA: 26.30000
• Density: 1.475g/cm³
• LogP: 4.05390
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Air Sensitive
• Solubility.: soluble in Toluene
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 275.97859
• Heavy Atom Count: 16
• Complexity: 216

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-(4-Bromophenoxy)benzaldehyde ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,N
• Statements: 41-43-51/53
• Safety Statements: 26-36/39-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C=O)OC2=CC=C(C=C2)Br

Technology Process of 4-(4-Bromophenoxy)benzaldehyde

There total 4 articles about 4-(4-Bromophenoxy)benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4-bromo-phenol (106-41-2) + 4-nitrobenzaldehdye (555-16-8) → 4-(4-bromophenoxy)benzaldehyde (69240-56-8)

Guidance literature:

With [Pd((η5-C5H5)Fe[(η5-C5H3)C(Me)=N(C6H4-4-Me)])(μ-Cl)]2; caesium carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 2h;

DOI:10.1002/aoc.3043

Reference yield: 94.0%

4-bromo-phenol (106-41-2) + 4-fluorobenzaldehyde (459-57-4) → 4-(4-bromophenoxy)benzaldehyde (69240-56-8)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 170 ℃; for 4h;

Reference yield: 86.0%

C11H13BBrO3(1-)*K(1+) + 4-nitrobenzaldehdye (555-16-8) → 4-(4-bromophenoxy)benzaldehyde (69240-56-8)

Guidance literature:

With Oxone; caesium carbonate; copper(II) oxide; In dimethyl sulfoxide; at 80 ℃; for 16h; Reagent/catalyst;

upstream raw materials:

4-bromo-phenol

4-fluorobenzaldehyde

4-Bromophenylboronic acid

4-nitrobenzaldehdye

Downstream raw materials:

1,2-dimethyl-1H-imidazole-4,5-dicarbonitrile

N-{(Z)-1,2-Dicyano-2-[1-methoxy-eth-(E)-ylideneamino]-vinyl}-acetimidic acid methyl ester

N'-[4-(4-bromophenoxy)benzylidene]pyridine-4-carbohydrazide

3-(((E)-[4-(4-bromophenoxy)phenyl]methylidene)amino)-2-methylquinazolin-4(3H)-one