BIS(BICYCLO(2.2.1)HEPTA-2,5-DIENE)-RHODIUM(I) PERCHLORATE

Base Information

Chemical Name:BIS(BICYCLO(2.2.1)HEPTA-2,5-DIENE)-RHODIUM(I) PERCHLORATE
CAS No.:60576-58-1
Molecular Formula:C14 H16 Rh . Cl O4
Molecular Weight:386.63294
Hs Code.:
Mol file:60576-58-1.mol

Synonyms:BIS(BICYCLO(2.2.1)HEPTA-2,5-DIENE)-RHODIUM(I) PERCHLORATE

Suppliers and Price of BIS(BICYCLO(2.2.1)HEPTA-2,5-DIENE)-RHODIUM(I) PERCHLORATE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of BIS(BICYCLO(2.2.1)HEPTA-2,5-DIENE)-RHODIUM(I) PERCHLORATE

Chemical Property:

PSA：74.27000
LogP:2.72730

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:E,Xi
Statements: 1-5-8-22-36/37/38
Safety Statements: 15-26-27-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of BIS(BICYCLO(2.2.1)HEPTA-2,5-DIENE)-RHODIUM(I) PERCHLORATE

There total 2 articles about BIS(BICYCLO(2.2.1)HEPTA-2,5-DIENE)-RHODIUM(I) PERCHLORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: bis(ethylene)rhodium(I) chloride dimer

: 60576-58-1
{Rh(NBD)2}ClO₄

Guidance literature:: In dichloromethane; acetone; filtn. under argon through Celite, evapn., dissolving in CH2Cl2, treatment with THF, addn. of hexane and standing for 2 h;
DOI:10.1021/om00094a025

Reference yield: 85.0%

: di-μ-chlorobis(norbornadiene)dirhodium(I)

: 121-46-0
bicyclo[2.2.1]hepta-2,5-diene

: silver perchlorate

: 60576-58-1
[(norbonadiene)2rhodium]ClO₄

Guidance literature:: In dichloromethane; for 1h; Inert atmosphere;
DOI:10.1021/ja403918w

Reference yield: 100.0%

: 60576-58-1
{Rh(NBD)2}ClO₄

: 125182-21-0
(2R,3S)-2-diphenylphosphinomethyl-3-diphenylphosphino-tetrahydropyran

: (norbornadiene)rhodium-(2R,3S)-2-diphenylphosphinomethyl-3-diphenylphosphino-tetrahydropyran perchlorate

Guidance literature:: In tetrahydrofuran; anaerobic conditions; stirring for 1 h at room temp.;; addn. of hexane; stirring for 1 h at 0°C; filtration; washing with cold hexane; elem. anal.;;
DOI:10.1016/0022-328X(89)87293-6