{rhodium(diphenylmethylphosphine)2(NBD)}perchlorate

Base Information

Chemical Name:{rhodium(diphenylmethylphosphine)2(NBD)}perchlorate
CAS No.:32799-81-8
Molecular Formula:C₃₃H₃₄P₂Rh*ClO₄
Molecular Weight:694.937
Hs Code.:

Synonyms:

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Chemical Property of {rhodium(diphenylmethylphosphine)2(NBD)}perchlorate

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Technology Process of {rhodium(diphenylmethylphosphine)2(NBD)}perchlorate

There total 1 articles about {rhodium(diphenylmethylphosphine)2(NBD)}perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 60576-58-1
{Rh(NBD)2}ClO₄

: 1486-28-8
diphenyl(methyl)phosphine

: 32799-81-8
{rhodium(diphenylmethylphosphine)2(NBD)}perchlorate

Guidance literature:: In dichloromethane; addn. of the phospine in small portions over 30 sec to a stirred soln. of the Rh compd. in deoxygenated CH2Cl2, stirring for 5 min and filtn. under Ar through Celite; washing with CH2Cl2, evapn., dropwise addn. of abs. deoxygenated diethyl ether, standing, filtn., washing with ether-CH2Cl2 (10:1) and ether and drying under a Ar flow; elem. anal.;
DOI:10.1021/om00094a025

Reference yield: 68.0%

: 32799-81-8
{rhodium(diphenylmethylphosphine)2(NBD)}perchlorate

: 868-85-9
Dimethyl phosphite

: bis(dimethyl phosphite)bis(methyldiphenylphosphine)rhodium(I) perchlorate diethyl ether solvate

Guidance literature:: With H₂; In methanol; Rh-complex was suspended in MeOH, system was evacuated, H2 admitted, stirred for 2 h, soln. of ligand in MeOH was added, stirred for 1 h; soln. was filtered, vol. was reduced, H2O was added dropwise, ppt. was filtered in air, washed with H2O, air dried; elem. anal.;

Reference yield:

: 32799-81-8
{rhodium(diphenylmethylphosphine)2(NBD)}perchlorate

: 112681-86-4
{rhodium(diphenylmethylphosphine)2(acetone)2}perchlorate

Guidance literature:: With hydrogen; acetone; In acetone; Rh compd. is dissolved in deoxygenated acetone and H2 is bubbled through the soln. for 2 min; evapn. (high vacuum);
DOI:10.1021/om00094a025