Diiodothulium

Base Information

• Chemical Name: Diiodothulium
• CAS No.: 60864-26-8
• Molecular Formula: I2Tm
• Molecular Weight: 422.74315
• European Community (EC) Number: 622-686-6
• DSSTox Substance ID: DTXSID40411818
• Wikidata: Q16857501
• Mol file: 60864-26-8.mol

Synonyms:Diiodothulium;60864-26-8;Thulium(II) iodide;THULIUM(II) IODIDE ANHYDROUS POWDER >;DTXSID40411818;Thulium(II) iodide, anhydrous, powder, >=99.9%

Chemical Property of Diiodothulium

Chemical Property:

• Melting Point: 756°C
• PSA: 0.00000
• LogP: 1.77140
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 422.74316
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Thulium(II) iodide anhydrous, powder, ≥99.9% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: I[Tm]I
• Uses: Promotes the cross-coupling of 2-acetylthiophene or ethyl 2-thiophenecarboxylate with aldehydes and ketones in THF at room temperature.

Technology Process of Diiodothulium

There total 5 articles about Diiodothulium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thulium (14041-47-5,14041-46-4,14333-45-0,15690-75-2,15720-75-9,15832-57-2,7440-30-4,13598-55-5,13981-30-1) + I3Tm → thulium(II) iodide (60864-26-8)

Guidance literature:

In neat (no solvent); at 851.84 ℃; Sealed tube;

DOI:10.1016/j.jallcom.2018.01.058

Reference yield:

thulium(III) iodide (13813-43-9) → thulium(II) iodide (60864-26-8)

Guidance literature:

With sodium; In N,N,N,N,N,N-hexamethylphosphoric triamide; dry box, argon atmosphere; lanthanide tri-iodide redn. by sodium soln. in hexamethylphosphortriamide;

Reference yield:

thulium (14041-47-5,14041-46-4,14333-45-0,15690-75-2,15720-75-9,15832-57-2,7440-30-4,13598-55-5,13981-30-1) + thulium(III) iodide (13813-43-9) → thulium(II) iodide (60864-26-8)

Guidance literature:

In solid; heating (720°C, 10 h);

upstream raw materials:

thulium

iodine

thulium(III) iodide