Magnesium trifluoromethanesulfonate

Base Information

• Chemical Name: Magnesium trifluoromethanesulfonate
• CAS No.: 60871-83-2
• Molecular Formula: C2F6MgO6S2
• Molecular Weight: 322.44
• Hs Code.: 29049090
• European Community (EC) Number: 629-253-0
• DSSTox Substance ID: DTXSID60370135
• Nikkaji Number: J261.104J
• Mol file: 60871-83-2.mol

Synonyms:Magnesium trifluoromethanesulfonate;60871-83-2;Magnesium triflate;MFCD00042601;magnesium;trifluoromethanesulfonate;Methanesulfonic acid, trifluoro-, magnesium salt;magnesiumtrifluoromethanesulfonate;Trifluoromethanesulfonic acid magnesium salt;magnesium trifiate;Magnesium trifluoromethanesulphonate;SCHEMBL244074;DTXSID60370135;BZQRBEVTLZHKEA-UHFFFAOYSA-L;AMY37808;AKOS015852938;GS-6866;SC10781;magnesium tris(fluoranyl)methanesulfonate;Magnesium trifluoromethanesulfonate, 97%;SY010228;FT-0628100;magnesium(2+) ion ditrifluoromethanesulfonate;T1304;D78219;A832932;MAGNESIUM TRIFLATE;MAGNESIUM TRIFLUOROMETHANESULFONATE;MAGNESIUM TRIFLUOROMETHANESULPHONATE;TRIFLUOROMETHANESULFONIC ACID MAGNESIUM SALT

Chemical Property of Magnesium trifluoromethanesulfonate

Chemical Property:

• Appearance/Colour: off-white to grey powder
• Melting Point: >=300 oC
• Boiling Point: 162 °C at 760 mmHg
• PSA: 131.16000
• LogP: 2.26440
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 0
• Exact Mass: 321.8890907
• Heavy Atom Count: 17
• Complexity: 145

Purity/Quality:

99%, ^*data from raw suppliers

Magnesium Trifluoromethanesulfonate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C,Xi
• Statements: 34-36/37/38
• Safety Statements: 26-36/37/39-45-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Mg+2]
• Uses: Magnesium trifluoromethanesulfonate is used as a component of the electrolyte, as lewis acid resulted in largely decreased and reversed enantioselectivities.

Refernces

Synthesis of 5-Fluoroprostacyclin

10.1021/jo00382a003

The research focuses on the synthesis of 5-fluoroprostacyclin, a stable and potent prostacyclin analogue, which is a significant advancement in the field due to its potential clinical applications as an inhibitor of platelet aggregation. The study aimed to overcome the limitations of prostacyclin's rapid hydration and inactivation by introducing a fluorine atom at the 5- or 7-carbon atom to achieve chemical stabilization. The process involved the reaction of protected prostacyclin derivatives with perchloryl fluoride in methanol, leading to the formation of 5-fluoro-6-methoxy derivatives. These were then separated, identified, and subjected to pyrolysis in the presence of magnesium triflate to yield 5(R)- or 5(S)-fluoro-A6-PGI2 derivatives. The study proposed a mechanism to explain the observed stereospecificity and concluded that the carbon-fluorine bond's stereoelectronic relationship with an adjacent carbonium ion is crucial in determining the product's configuration.

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