Synthesis of 5-Fluoroprostacyclin

DOI: 10.1021/jo00382a003

Source and publish data:

Journal of Organic Chemistry p. 978 - 990 (1987)

Update date:2022-09-26

Topics: Synthesis Catalyst Reactant

Authors:

Djuric, Stevan W.

Garland, Robert B.

Nysted, Leonard D.

Pappo, Raphael

Plume, Gatis

Swenton, Lydia

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Article abstract of DOI:10.1021/jo00382a003

Protected prostacyclin derivatives were reacted with perchloryl fluoride in methanol.The resultant 5-fluoro-6-methoxy derivatives were separated and identified.Pyrolysis of the individual isomers in the presence of magnesium triflate led to 5(R)- or 5(S)-

Full text of DOI:10.1021/jo00382a003

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