o-(Phenylazo)benzenesulphenyl bromide

Base Information

• Chemical Name: o-(Phenylazo)benzenesulphenyl bromide
• CAS No.: 2849-62-9
• Molecular Formula: C12H9 Br N2 S
• Molecular Weight: 293.187
• Hs Code.: 2930909090
• European Community (EC) Number: 220-654-2
• DSSTox Substance ID: DTXSID501280058
• Nikkaji Number: J159G
• Mol file: 2849-62-9.mol

Synonyms:2849-62-9;Azobenzene-2-sulfenyl bromide;o-(Phenylazo)benzenesulphenyl bromide;(2-phenyldiazenylphenyl) thiohypobromite;AZOBENZENE-2-SULFENYL BROMIDE*;Benzenesulfenyl bromide, 2-(phenylazo)-;EINECS 220-654-2;[2-(bromosulfanyl)phenyl](phenyl)diazene;Azobenzol-2-sulfenylbromid;SCHEMBL8128454;C12-H9-Br-N2-S;DTXSID501280058;Benzenesulfenyl bromide, o-(phenylazo)-;Benzenesulfenylbromide, 2-(phenylazo)-(9CI);2-[(E)-Phenyldiazenyl]benzenesulfenyl bromide #

Chemical Property of o-(Phenylazo)benzenesulphenyl bromide

Chemical Property:

• Vapor Pressure: 3.47E-06mmHg at 25°C
• Melting Point: 215-220oC (dec.)
• Boiling Point: 398.1°C at 760 mmHg
• Flash Point: 194.6°C
• PSA: 50.02000
• Density: 1.42g/cm³
• LogP: 5.50400
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 291.96698
• Heavy Atom Count: 16
• Complexity: 229

Purity/Quality:

99% ^*data from raw suppliers

AZOBENZENE-2-SULFENYL BROMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 23/24/25
• Safety Statements: 36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)N=NC2=CC=CC=C2SBr

Technology Process of o-(Phenylazo)benzenesulphenyl bromide

There total 4 articles about o-(Phenylazo)benzenesulphenyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 2-phenylazo-benzenesulfenyl bromide (2849-62-9)

Guidance literature:

With water; hydrogen bromide; acetic acid;

DOI:10.1021/ja01601a078

Reference yield:

2-(phenylazo)phenyl benzyl thioether (101418-87-5) → 2-phenylazo-benzenesulfenyl bromide (2849-62-9)

Guidance literature:

With hydrogen bromide; bromine; acetic acid;

DOI:10.1039/jr9540000090

Reference yield:

Nitrosobenzene (586-96-9) → 2-phenylazo-benzenesulfenyl bromide (2849-62-9)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic acid

2: acetic acid; bromine

With bromine; acetic acid;

DOI:10.1039/jr9540000090

upstream raw materials:

2-(phenylazo)phenyl benzyl thioether

Nitrosobenzene

2-(benzylsulfanyl)aniline

Downstream raw materials:

(2-methylsulfanyl-phenyl)-phenyl-diazene

2-phenylazo-benzenesulfenyl iodide

2-phenylazo-benzenesulfenyl chloride

(2-methanesulfinyl-phenyl)-phenyl-diazene