dicarbonylbis(pentafluorothiophenolato)bis(methyldiphenylphosphine)ruthenium(II)

Base Information

• Chemical Name: dicarbonylbis(pentafluorothiophenolato)bis(methyldiphenylphosphine)ruthenium(II)
• CAS No.: 118401-42-6
• Molecular Formula: C₄₀H₂₆F₁₀O₂P₂RuS₂
• Molecular Weight: 955.779
• Mol file: 118401-42-6.mol

Synonyms:

Chemical Property of dicarbonylbis(pentafluorothiophenolato)bis(methyldiphenylphosphine)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonylbis(pentafluorothiophenolato)bis(methyldiphenylphosphine)ruthenium(II)

There total 2 articles about dicarbonylbis(pentafluorothiophenolato)bis(methyldiphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

dicarbonylbis(methyldiphenylphosphine)dichlororuthenium(II) (118456-89-6,25165-52-0,40537-28-8,60426-66-6,60426-67-7) + lead pentafluorothiophenolate (21459-27-8) → dicarbonylbis(pentafluorothiophenolato)bis(methyldiphenylphosphine)ruthenium(II) (118401-42-6,118456-85-2)

Guidance literature:

With carbon monoxide; In acetone; byproducts: PbCl2; shaking the mixt. under CO for 10 h;; removal of PbCl2 by filtration; concg. the soln.; addn. of CH3OH; filtration; washing with CH3OH/diethyl ether; vacuum drying; elem. anal.;

DOI:10.1016/0022-328X(88)80646-6

Reference yield: 40.0%

ruthenium(III) chloride trihydrate (14898-67-0) + lead pentafluorothiophenolate (21459-27-8) + diphenyl(methyl)phosphine (1486-28-8) → dicarbonylbis(pentafluorothiophenolato)bis(diphenylmethylphosphine)ruthenium(II) (118401-42-6,118456-85-2)

Guidance literature:

With carbon monoxide; In ethanol; reflux the mixt. for 5 min; then shaking the mixt. under CO after addn. of lead pentafluorothiophenolate;; evapg. the soln. to dryness; residue recrystd. from acetone/CH3OH; filtration; washing with acetone; vacuum drying; elem. anal.;

DOI:10.1016/0022-328X(88)80646-6

upstream raw materials:

ruthenium(III) chloride trihydrate

lead pentafluorothiophenolate

diphenyl(methyl)phosphine

dicarbonylbis(methyldiphenylphosphine)dichlororuthenium(II)