(benzoato)tricarbonyl(η5-cyclopentadienyl)tungsten

Base Information

Chemical Name:(benzoato)tricarbonyl(η5-cyclopentadienyl)tungsten
CAS No.:108451-97-4
Molecular Formula:C₁₅H₁₀O₅W
Molecular Weight:454.091
Hs Code.:

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Chemical Property of (benzoato)tricarbonyl(η5-cyclopentadienyl)tungsten

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Technology Process of (benzoato)tricarbonyl(η5-cyclopentadienyl)tungsten

There total 1 articles about (benzoato)tricarbonyl(η5-cyclopentadienyl)tungsten which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: tricarbonyl(cyclopentadienyl)methyltungsten(II)

: 65-85-0,8013-63-6
benzoic acid

: bis(tricarbonyl(η-cyclopentadienyl)tungsten)

: 108451-97-4
(benzoato)tricarbonyl(η5-cyclopentadienyl)tungsten

Guidance literature:: With K₂CO₃; HBF₄; In diethyl ether; dichloromethane; addn. of PhCOOH and HBF4 in ether to a soln. of W-complex in CH2Cl2 (under N2), addn. of K2CO3 when gas evolution has ceased, stirring for 30 min at room temp.; evapn. in vac., extn. with ether, evapn. of extracts to dryness, dissolution in C6H6, chromy., elution (C6H6) yields byproduct, elution (THF, orange fraction), evapn. in vac., washing with pentane (several times), drying in vac., elem. anal.;

Reference yield: 87.0%

: 108-89-4
picoline

: 108451-97-4
(benzoato)tricarbonyl(η5-cyclopentadienyl)tungsten

: 533-01-7,2989-37-9,3113-85-7,14067-34-6,14604-51-4,113596-35-3
Copper(I); benzoate

: 108451-98-5
di-μ-benzoato-dicarbonyl(η5-cyclopentadienyl)((4-methylpyridine)copper)tungsten(Cu-W)

Guidance literature:: In benzene; addn. of Cu(O2CPh)and MeC5H4N to a soln. of W-complex in benzene (underN2, at room temp.), stirring for 36 h; filtration through silica gel, evapn. of solvent in vac., recrystn. from benzene/pentane (two times), elem. anal.;