Re(VI)(.tplbond.C-2,4,6-C₆H₂Me₃)(PPh₃)(H₂O)Br₃

Base Information

• Chemical Name: Re(VI)(.tplbond.C-2,4,6-C₆H₂Me₃)(PPh₃)(H₂O)Br₃
• CAS No.: 199189-36-1
• Molecular Formula: C₂₈H₂₈Br₃OPRe
• Molecular Weight: 837.422
• Mol file: 199189-36-1.mol

Synonyms:

Chemical Property of Re(VI)(.tplbond.C-2,4,6-C₆H₂Me₃)(PPh₃)(H₂O)Br₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Re(VI)(.tplbond.C-2,4,6-C₆H₂Me₃)(PPh₃)(H₂O)Br₃

There total 1 articles about Re(VI)(.tplbond.C-2,4,6-C₆H₂Me₃)(PPh₃)(H₂O)Br₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

[Re(V)(.tplbond.C-2,4,6-C6H2Me3)(PPh3)2(CO)(H2O)Cl]ClO4 (180776-56-1) + 1,1-dibromomethane (74-95-3) → Re(VI)(.tplbond.C-2,4,6-C6H2Me3)(PPh3)(H2O)Br3 (199189-36-1)

Guidance literature:

In further solvent(s); Irradiation (UV/VIS); in deoxygenated CH2Br2, 350 nm Hg-lamp, room temp., 30 h; evapn. (vac.), recrystn. (CH2Cl2/petroleum ether); elem. anal.;

DOI:10.1021/ic970342e

upstream raw materials:

[Re(V)(.tplbond.C-2,4,6-C₆H₂Me₃)(PPh₃)2(CO)(H₂O)Cl]ClO₄

1,1-dibromomethane