α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal

Base Information

• Chemical Name: α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal
• CAS No.: 34234-86-1
• Molecular Formula: C₁₂H₁₈NO₂
• Molecular Weight: 208.28
• Mol file: 34234-86-1.mol

Synonyms:

Chemical Property of α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal

There total 6 articles about α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-tert-butyl-α-phenylnitrone (3376-24-7,68315-30-0) + 4-cyano-1-methoxypyridin-1-ium tetrafluoroborate → α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal (34234-86-1)

Guidance literature:

With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; In acetonitrile; at 24.84 ℃; Irradiation;

DOI:10.1002/anie.201806296

Reference yield:

methane (34557-54-5,27936-85-2) + N-tert-butyl-α-phenylnitrone (3376-24-7,68315-30-0) → α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal (34234-86-1)

Guidance literature:

With ammonia; water; at 40 ℃; Irradiation;

DOI:10.1039/ft9908602565

Reference yield:

N-tert-butyl-α-phenylnitrone (3376-24-7,68315-30-0) + C27H25N5O6 → α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal (34234-86-1) + C37H37N4O6

Guidance literature:

In benzene; Photolysis;

DOI:10.1021/jacs.8b12254

upstream raw materials:

methanol

(Z)-N-benzylidene-2-methylpropan-2-amine oxide

methane

N-tert-butyl-α-phenylnitrone

Refernces

• 1、 Jelier, Benson J.,Tripet, Pascal F.,Pietrasiak, Ewa,Franzoni, Ivan,Jeschke, Gunnar,Togni, Antonio. "Radical Trifluoromethoxylation of Arenes Triggered by a Visible-Light-Mediated N?O Bond Redox Fragmentation". supporting information. p. 13784 - 13789. Retrieved 2018/09/14.
• 2、 Fadnis, Anand G.,Kemp, Terence J.. "Photo-oxidation of Alcohols by Hexachlorometalate(IV) Ions (M = Pt, Pd, or Ir): Spin Trapping and Matrix Isolation Electron Spin Resonance Studies". . p. 1237 - 1240. Retrieved 2007/10/02.