chloro-bis(diphenylphosphinoethyl)aminepalladium(II) chloride

Base Information

• Chemical Name: chloro-bis(diphenylphosphinoethyl)aminepalladium(II) chloride
• CAS No.: 763038-49-9
• Molecular Formula: C₂₈H₂₉ClNP₂Pd*Cl
• Molecular Weight: 618.818
• Mol file: 763038-49-9.mol

Synonyms:

Chemical Property of chloro-bis(diphenylphosphinoethyl)aminepalladium(II) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloro-bis(diphenylphosphinoethyl)aminepalladium(II) chloride

There total 3 articles about chloro-bis(diphenylphosphinoethyl)aminepalladium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.2%

bis(acetonitrile)palladium(II) dichloride + bis(2-(diphenylphosphino)ethyl)amine hydrochloride (66534-97-2) → chloro-bis(diphenylphosphinoethyl)aminepalladium(II) chloride (763038-49-9,112153-51-2)

Guidance literature:

In tetrahydrofuran; Ar atm.; equimolar amts., stirring (room temp., overnight); evapn. (vac.), recrystn. (THF); elem. anal.;

DOI:10.1002/(SICI)1521-3749(199906)625:6<923::AID-ZAAC923>3.0.CO;2-R

Reference yield: 72.0%

dichloro(cycloocta-1,5-diene)palladium (II) (12107-56-1) + bis(2-(diphenylphosphino)ethyl)amine hydrochloride (66534-97-2) → chloro-bis(diphenylphosphinoethyl)aminepalladium(II) chloride (763038-49-9,112153-51-2)

Guidance literature:

In benzene; DPEA*HCl was dissolved in benzene under nitrogen atmosphere. PdCl2(COD) was added to the above soln. in powder form after approx. 0.5 h when a clear soln. was obtained. The refluxing was continued until a crystalline compd. separated out.; The compd. was cooled overnight, filtered and washed thoroughly with benzene. Recrystn. from CH2Cl2-n-hexane mixt.. Elem.anal.;

DOI:10.1016/0304-5102(88)80062-2

Reference yield:

bis(2-(diphenylphosphino)ethyl)amine hydrochloride (66534-97-2) + palladium dichloride → chloro-bis(diphenylphosphinoethyl)aminepalladium(II) chloride (763038-49-9,112153-51-2) + bis(bis(2-diphenylphosphino)ethyl)aminepalladium(II) chloride

Guidance literature:

In methanol; refluxing;;

DOI:10.1016/S0277-5387(00)86543-2

upstream raw materials:

dichloro(cycloocta-1,5-diene)palladium (II)

bis(2-(diphenylphosphino)ethyl)amine hydrochloride

Downstream raw materials:

{PdIV(bis(2-diphenylphosphinoethyl)amine)(H)3}⁽¹⁺⁾

{PdII(bis(2-diphenylphosphinoethyl)amine)(H)}⁽¹⁺⁾