Ru(CO)4(P(C₆H₅)2CH₃)

Base Information

Chemical Name:Ru(CO)4(P(C₆H₅)2CH₃)
CAS No.:57894-45-8
Molecular Formula:C₁₇H₁₃O₄PRu
Molecular Weight:413.332
Hs Code.:

Ru(CO)4(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>3</sub>)

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ru(CO)4(P(C₆H₅)2CH₃)

Chemical Property:

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Technology Process of Ru(CO)4(P(C₆H₅)2CH₃)

There total 3 articles about Ru(CO)4(P(C₆H₅)2CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 1486-28-8
diphenyl(methyl)phosphine

: 57894-45-8
Ru(CO)4(P(C₆H₅)2CH₃)

Guidance literature:: With CO; In petroleum ether; Irradiation (UV/VIS); soln. stirred under CO for 30 min, irradn. (mercury lamp) for about 1 h until colorless, exchange of CO by N2, addn. of phosphine, stirred overnight at room temp.; concn., column chromy. (silica gel), elution with ligroin/CH2Cl2 (19/1), elution with ligroin/CH2Cl2 (7/3) yields Ru(CO)4(PR3) (yellow oil), crystn. (hexane) at -60°C;

Reference yield:

: Ru₂(Me)(I)(CO)4(PMePh₂)(i-Pr-DAB)

: trans,cis-[RuI(methyl)(CO)2(N,N'-diisopropyl-1,4-diazabutadiene)]

: trans,cis-[RuI(COCH₃)(CO)2(N,N'-diisopropyl-1,4-diazabutadiene)]

: 57894-45-8
Ru(CO)4(P(C₆H₅)2CH₃)

Guidance literature:: With CO; In hexane; dichloromethane; dissolved in hexane/CH2Cl2 (9/1), stirred under CO at 45°C for 5-10 h; column chromy. (silica gel), elution with ligroin/CH2Cl2 (7/3) yields Ru(CO)4(PR3) complex, elution with CH2Cl2/CH3CN (9/1) yields Ru(Me)(I)(CO)2(i-Pr-DAB) and Ru(C(O)Me)(I)(CO)2(i-Pr-DAB), react. monitored by IR spect.;

Reference yield:

: Ru₂(Me)(I)(CO)4(i-Pr-DAB)

: 1486-28-8
diphenyl(methyl)phosphine

: trans,cis-[RuI(methyl)(CO)2(N,N'-diisopropyl-1,4-diazabutadiene)]

: trans,cis-[RuI(COCH₃)(CO)2(N,N'-diisopropyl-1,4-diazabutadiene)]

: Ru₂(Me)(I)(CO)4(P(n-Bu)3)(i-Pr-DAB)

: 57894-45-8
Ru(CO)4(P(C₆H₅)2CH₃)

Guidance literature:: With CO; In chloroform-d1; High Pressure; under N2, soln. filtered over Celite into NMR-tube, pressurized with CO for 20 min (6-36 bar), tube closed, react. at 45°C for 45 min (36 bar) to 180 min (6 bar), subsequent conversion of methyl to acetyl complex within 8-10 h; react. monitored by NMR spect.;