CoFe₂(CC₆H₄CH₃)(CO)6((C₆H₅)2PCH₂P(C₆H₅)2)2

Base Information

• Chemical Name: CoFe₂(CC₆H₄CH₃)(CO)6((C₆H₅)2PCH₂P(C₆H₅)2)2
• CAS No.: 106972-28-5
• Molecular Formula: C₆₄H₅₁CoFe₂O₆P₄
• Molecular Weight: 1210.69
• Mol file: 106972-28-5.mol

Synonyms:

Chemical Property of CoFe₂(CC₆H₄CH₃)(CO)6((C₆H₅)2PCH₂P(C₆H₅)2)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of CoFe₂(CC₆H₄CH₃)(CO)6((C₆H₅)2PCH₂P(C₆H₅)2)2

There total 1 articles about CoFe₂(CC₆H₄CH₃)(CO)6((C₆H₅)2PCH₂P(C₆H₅)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

[CoFe2(CC6H4CH3)(CO)10] (106972-25-2) + bis-diphenylphosphinomethane (2071-20-7) → CoFe2(CC6H4CH3)(CO)6((C6H5)2PCH2P(C6H5)2)2 (106972-28-5) + CoFe2(CC6H4CH3)(CO)8((C6H5)2PCH2P(C6H5)2) (106972-27-4)

Guidance literature:

In dichloromethane; (O2-free N2); mixt. of CoFe2 compd. (0.40 mmol) and dppm (0.80 mmol) inlight petroleum stirred at room temp. for 5 d; solvent removed (vac.); chromy. on Kieselgel column (CH2Cl2/light petroleum 1/1); 1st band (dark brown) = the (dppm)1 complex; 2nd band (dark green) evapd. (vac.) giving the (dppm)2 complex (microcrystals); elem. anal.;

DOI:10.1039/DT9860001723

Reference yield: 94.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + CoFe2(CC6H4CH3)(CO)6((C6H5)2PCH2P(C6H5)2)2 (106972-28-5) → CoFe2(H)(CC6H4CH3)(CO)6((C6H5)2PCH2P(C6H5)2)2(1+)*BF4(1-) = [CoFe2(H)(CC6H4CH3)(CO)6((C6H5)2PCH2P(C6H5)2)2][BF4]

Guidance literature:

In dichloromethane; (O2-free N2); CoFe2 compd. (0.25 mmol) in CH2Cl2 protonated with HBF4*Et2O (0.1 mL, ca. 0.25 mmol); stirring for 30 min; solvent removed (vac.); residue washed (Et2O); crystn. (CH2Cl2/light petroleum = 1/1); elem. anal.;

DOI:10.1039/DT9860001723

upstream raw materials:

[CoFe₂(CC₆H₄CH₃)(CO)10]

bis-diphenylphosphinomethane