PhCMe₂CH₂(C₅H₂N)(C(CH₃)N(C₆H₃)(iPr)2)2

Base Information

• Chemical Name: PhCMe₂CH₂(C₅H₂N)(C(CH₃)N(C₆H₃)(iPr)2)2
• CAS No.: 929103-59-3
• Molecular Formula: C₄₃H₅₅N₃
• Molecular Weight: 613.93
• Mol file: 929103-59-3.mol

Synonyms:

Chemical Property of PhCMe₂CH₂(C₅H₂N)(C(CH₃)N(C₆H₃)(iPr)2)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PhCMe₂CH₂(C₅H₂N)(C(CH₃)N(C₆H₃)(iPr)2)2

There total 1 articles about PhCMe₂CH₂(C₅H₂N)(C(CH₃)N(C₆H₃)(iPr)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine (204203-14-5) → PhCMe2CH2(C5H2N)(C(CH3)N(C6H3)(iPr)2)2 (929103-59-3)

Guidance literature:

N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine; [{Mn(CH₂CMe₂Ph)2}2]; In toluene; Inert atmosphere;

With methanol; In benzene-d6; Inert atmosphere;

DOI:10.1002/chem.201001428

Reference yield: 85.0%

iron(II) chloride tetrahydrate + PhCMe2CH2(C5H2N)(C(CH3)N(C6H3)(iPr)2)2 (929103-59-3) → FeCl2(PhCMe2CH2(C5H2N)(C(CH3)N(C6H3)(iPr)2)2) (1152183-03-3)

Guidance literature:

In tetrahydrofuran; under O2-free N2, Schlenk techniques; soln. of org. ligand (1.1 mmol) added dropwise to suspn. of FeCl2*4H2O (1 mmol) (room temp., stirring); stirred (24 h, room temp.); filtered; washed with hexane; dried (vac.);

DOI:10.1002/ejic.200701220

Reference yield: 58.0%

PhCMe2CH2(C5H2N)(C(CH3)N(C6H3)(iPr)2)2 (929103-59-3) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → CoCl2(PhCMe2CH2(C5H2N)(C(CH3)N(C6H3)(iPr)2)2) (1152183-06-6)

Guidance literature:

In tetrahydrofuran; under O2-free N2, Schlenk techniques; soln. of org. ligand (1.1 mmol) added dropwise to suspn. of CoCl2 (1 mmol) (room temp., stirring); stirred(24 h, room temp.); filtered; washed with hexane; dried (vac.); recrystd. from CH2Cl2/hexane(9:1) at -30°C; elem. anal.;

DOI:10.1002/ejic.200701220

upstream raw materials:

N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine

Downstream raw materials:

FeCl₂(PhCMe₂CH₂(C₅H₂N)(C(CH₃)N(C₆H₃)(iPr)2)2)

CoCl₂(PhCMe₂CH₂(C₅H₂N)(C(CH₃)N(C₆H₃)(iPr)2)2)