2,6-Bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine

Base Information

• Chemical Name: 2,6-Bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine
• CAS No.: 204203-14-5
• Molecular Formula: C33H43N3
• Molecular Weight: 481.725
• European Community (EC) Number: 803-209-2
• Nikkaji Number: J953.374E
• Mol file: 204203-14-5.mol

Synonyms:204203-14-5;2,6-BIS[1-(2,6-DIISOPROPYLPHENYLIMINO)ETHYL]PYRIDINE;2,6-Bis-[1-(2,6-diisopropylphenylimino)ethyl]pyridine;2,6-BIS[1-(2,6-DI-I-PROPYLPHENYLIMINO)ETHYL]PYRIDINE;N-[2,6-di(propan-2-yl)phenyl]-1-[6-[N-[2,6-di(propan-2-yl)phenyl]-C-methylcarbonimidoyl]pyridin-2-yl]ethanimine;iPrPDI;SCHEMBL808792;NVPUVWBDTWBFRF-UHFFFAOYSA-N;MFCD01862436;SC11805;BS-52199;CS-0087401;FT-0643904;E77210;J-400189;2,6-bis[1-(2,6-di-iso-propylphenylimino)ethyl]pyridine;(2,6-bis[1-[(2,6-diisopropylphenyl)imino]ethyl]pyridine);2,6-Bis-[1-(2,6-diisopropylphenylimino)ethyl]pyridine, AldrichCPR;(N,N'E,N,N'E)-N,N'-(1,1'-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene))bis(2,6-diisopropylaniline)

Chemical Property of 2,6-Bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine

Chemical Property:

• Vapor Pressure: 1.44E-12mmHg at 25°C
• Boiling Point: 573.6ºC at 760 mmHg
• PKA: 3.21±0.50(Predicted)
• Flash Point: 300.7ºC
• PSA: 37.61000
• Density: 0.99g/cm3
• LogP: 9.85660
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• XLogP3: 9.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 8
• Exact Mass: 481.345698384
• Heavy Atom Count: 36
• Complexity: 641

Purity/Quality:

98%Min ^*data from raw suppliers

2,6-Bis[1-(2,6-di-i-propylphenylimino)ethyl]pyridine, 98% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1=C(C(=CC=C1)C(C)C)N=C(C)C2=NC(=CC=C2)C(=NC3=C(C=CC=C3C(C)C)C(C)C)C

Technology Process of 2,6-Bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine

There total 8 articles about 2,6-Bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2,6-Diacetylpyridine (1129-30-2) + 2,6-diisopropylbenzenamine (24544-04-5) → N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine (204203-14-5)

Guidance literature:

With formic acid; sodium sulfate; In dichloromethane; for 72h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1002/chem.201304459

Reference yield: 43.0%

2,6-Diacetylpyridine (1129-30-2) + 2,6-diisopropylbenzenamine (24544-04-5) → N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine (204203-14-5) + 1-(6-(1-((2,6-diisopropylphenyl)imino)ethyl)pyridin-2-yl)ethan-1-one

Guidance literature:

toluene-4-sulfonic acid; In methanol; Reflux;

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + [Ti(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Cl3]Cl (850196-08-6,850196-05-3) → tetrachlorobis(tetrahydrofuran)titanium(IV) (31011-57-1,112925-19-6,112925-18-5) + N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine (204203-14-5)

Guidance literature:

In tetrahydrofuran; under Ar; Ti complex treated with THF; refluxed for 2 h; solvent removed in vac.; detd. by IR and (1)H NMR spectra;

DOI:10.1039/b415997g

upstream raw materials:

tetrahydrofuran

[Ti(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Cl₃]Cl

C₃₃H₄₃CoN₆

2,6-Diacetylpyridine

Downstream raw materials:

AlCl₂(C₅H₃N(CCH₃NC₆H₃(CH(CH₃)2)2)2)⁽¹⁺⁾*AlCl₄^(1-)*C₆H₅CH₃=[AlCl₂(C₅H₃N(CCH₃NC₆H₃(CH(CH₃)2)2)2)][AlCl₄]*C₆H₅CH₃

[Fe(CH₂SiMe₃)₂(^iPrBIP)]

([2,6-[2,6(i-Pr)2PhN=C(CH₃)]2-(2-CH₂SiMe₃))(C₅H₃N)Fe(CH₂SiMe₃)

(2-[2,6(i-Pr)2PhN=C(CH₃)]-6-[2,6-(i-Pr)2PhNC(CH₃)(CH₂SiMe₃)](C₅H₃N))Fe(CH₂SiMe₃)