trans-[PdIPh(AsPh₃)2]

Base Information

Chemical Name:trans-[PdIPh(AsPh₃)2]
CAS No.:352670-77-0
Molecular Formula:C₄₂H₃₅As₂IPd
Molecular Weight:922.908
Hs Code.:

Synonyms:

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Chemical Property of trans-[PdIPh(AsPh₃)2]

Chemical Property:

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Technology Process of trans-[PdIPh(AsPh₃)2]

There total 4 articles about trans-[PdIPh(AsPh₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 52522-40-4
tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex

: 591-50-4
iodobenzene

: 198766-52-8
rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-(tributylstannyl)ferrocene

: 603-32-7
triphenyl-arsane

: 352670-77-0,78622-84-1
trans-[PdIPh(AsPh₃)2]

: 942472-59-5
rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene

: 36234-31-8,34845-97-1
trans-[Pd(I)2(AsPh₃)2]

: rac-2,2'-bis[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-1,1'-biferrocene

Guidance literature:: With CuI; In N,N-dimethyl-formamide; (N2, a hood) into a Schlenk tube were weighted Fe-complex, then Pd-complex, CuI and As(C6H5)3, evacuated, filled N2, the mixt. was suspd. in DMF, freshly distilled C6H5I was added, the mixt. was stirred for 14 h at 70°C, cooled to room temp.; KF and then distilled H2O were added, stirred for 30 min at room temp., the solid was washed with ethyl acetate, diluted with ethyl acetate, washed eight times with brine, dried (MgSO4), concd., layered with pentane,crystd. overnight at -30°C;
DOI:10.1002/hlca.200790083

Reference yield:

: 591-50-4
iodobenzene

: 352670-77-0,78622-84-1
trans-[PdIPh(AsPh₃)2]

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: d₇-N,N-dimethylformamide

In tetrahydrofuran; d₇-N,N-dimethylformamide;
DOI:10.1021/ja0204978

Reference yield:

: 524697-04-9,503616-14-6
trans-Ph2Pd2(μ(2)-I)2(AsPh3)2

: 603-32-7
triphenyl-arsane

: 352670-77-0,78622-84-1
trans-[PdIPh(AsPh₃)2]

Guidance literature:: In d₇-N,N-dimethylformamide; under dry Ar atm. using Schlenk techniques; to Pd dimer added 4-5 equivsof AsPh3; not isolated; monitored by NMR;
DOI:10.1021/ja0204978