rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene

Base Information

Chemical Name:rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene
CAS No.:942472-59-5
Molecular Formula:C₂₅H₁₉FeNO₂
Molecular Weight:421.278
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene

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Technology Process of rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene

There total 1 articles about rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 52522-40-4
tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex

: 591-50-4
iodobenzene

: 198766-52-8
rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-(tributylstannyl)ferrocene

: 603-32-7
triphenyl-arsane

: 352670-77-0,78622-84-1
trans-[PdIPh(AsPh₃)2]

: 942472-59-5
rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene

: 36234-31-8,34845-97-1
trans-[Pd(I)2(AsPh₃)2]

: rac-2,2'-bis[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-1,1'-biferrocene

Guidance literature:: With CuI; In N,N-dimethyl-formamide; (N2, a hood) into a Schlenk tube were weighted Fe-complex, then Pd-complex, CuI and As(C6H5)3, evacuated, filled N2, the mixt. was suspd. in DMF, freshly distilled C6H5I was added, the mixt. was stirred for 14 h at 70°C, cooled to room temp.; KF and then distilled H2O were added, stirred for 30 min at room temp., the solid was washed with ethyl acetate, diluted with ethyl acetate, washed eight times with brine, dried (MgSO4), concd., layered with pentane,crystd. overnight at -30°C;
DOI:10.1002/hlca.200790083

Reference yield: 89.0%

: 79785-97-0
hydrazine hydrate

: 942472-59-5
rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene

: 942472-60-8
rac-1-(aminomethyl)-2-phenylferrocene

Guidance literature:: In ethanol; byproducts: phthalazine-1,4-dione; (N2, Schlenk, a hood) to a suspn. of complex and hydrazine hydrate in ethanol was refluxed for 75 min at 95°C, cooled to room temp.; diethyl ether was added, the soln. was concd., dissolved in diethyl ether, washed twice with brine, dried (MgSO4), concd., flash chromy. (silicagel, hexanes/CH2Cl2 1:5+10% (C2H5)3N), as oil; elem. anal.;
DOI:10.1002/hlca.200790083