C₁₃H₁₉⁽²⁾HO₂S

Base Information

• Chemical Name: C₁₃H₁₉⁽²⁾HO₂S
• CAS No.: 1593771-88-0
• Molecular Formula: C₁₃H₂₀O₂S
• Molecular Weight: 241.359
• Mol file: 1593771-88-0.mol

Synonyms:

Chemical Property of C₁₃H₁₉⁽²⁾HO₂S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₃H₁₉⁽²⁾HO₂S

There total 3 articles about C₁₃H₁₉⁽²⁾HO₂S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methylhex-4-yl phenyl sulfone (1593771-59-5) → C13H19(2)HO2S (1593771-88-0) + C13H19(2)HO2S (1593771-90-4)

Guidance literature:

2-methylhex-4-yl phenyl sulfone; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; at -78 ℃; for 0.166667h;

With water-d2; In tetrahydrofuran; at -78 ℃; regioselective reaction; Inert atmosphere;

DOI:10.1002/ejoc.201301553

Reference yield:

1-phenylsulphonyl-3-methyl butane (52075-20-4) → C13H19(2)HO2S (1593771-88-0) + C13H19(2)HO2S (1593771-90-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / hexane; tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

1.2: 0.17 h / -78 - -40 °C / Inert atmosphere

2.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / tetrahydrofuran / 0.17 h / -78 °C

2.2: -78 °C / Inert atmosphere

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane;

DOI:10.1002/ejoc.201301553

Reference yield:

methylphenylsulfonate (3112-85-4) → C13H19(2)HO2S (1593771-88-0) + C13H19(2)HO2S (1593771-90-4)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / hexane; tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

1.2: 0.17 h / -78 - -60 °C / Inert atmosphere

2.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / hexane; tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere

2.2: 0.17 h / -78 - -40 °C / Inert atmosphere

3.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / tetrahydrofuran / 0.17 h / -78 °C

3.2: -78 °C / Inert atmosphere

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane;

DOI:10.1002/ejoc.201301553

upstream raw materials:

2-methylhex-4-yl phenyl sulfone

methylphenylsulfonate

1-phenylsulphonyl-3-methyl butane