52075-20-4Relevant articles and documents
Mechanistic studies of reactive oxygen species mediated electrochemical radical reactions of alkyl iodides
Li, Diyuan,Ma, Tsz-Kan,Wilden, Jonathan D.
supporting information, p. 8356 - 8359 (2021/08/25)
Mechanistic studies of a reactive oxygen species mediated electrochemical radical reaction of alkyl iodides are described. Hydroxyl radicals and ozone are identified to be the active species involved in the formation of alkyl radicals under mildly reducing potential (-1.0 V vs. Ag QRE) in buffered acidic conditions (pH 3.6).
Alkyl radical precursor and application thereof in establishing C-C bond
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Paragraph 0108; 0109; 0132, (2018/09/14)
The invention provides a precursor for generating an alkyl radical based on the visible light induction and a novel method for generating the radical. The alkyl sulfenamide is used as the radical precursor to generate the alkyl radical by virtue of the C-S bond cracking accelerated by the visible light, and then the alkyl radical is applied to the chemical reaction for establishing a C-C bond. Thereaction system has the characteristic of high efficiency, and has important scientific significance and application value for researching the novel C-C bond formation reaction, organic synthesis, drug synthesis and the like. In general, the invention provides a novel general method having practical application value. The thioalcohol (thioether) with rich resources is converted to a tool for derivating the alkyl radical.
Vitamin B12 Catalyzed Atom Transfer Radical Addition
Proinsias, Keith O.,Jackowska, Agnieszka,Radzewicz, Katarzyna,Giedyk, MacIej,Gryko, Dorota
supporting information, p. 296 - 299 (2018/01/17)
Vitamin B12, a natural Co-complex, catalyzes atom transfer radical addition (ATRA) of organic halides to olefins. The established conditions were found to be very selective, with atom transfer radical polymerization (ATRP) occurring only in the case of acrylates.