(2S,3R,4Z)-1-(5a-carba-β-D-glucopyranosylamino)-2-(2,4-dinitrophenyl)amino-4-octadecen-3-ol

Base Information

Chemical Name:(2S,3R,4Z)-1-(5a-carba-β-D-glucopyranosylamino)-2-(2,4-dinitrophenyl)amino-4-octadecen-3-ol
CAS No.:162119-28-0
Molecular Formula:C₃₁H₅₂N₄O₉
Molecular Weight:624.775
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3R,4Z)-1-(5a-carba-β-D-glucopyranosylamino)-2-(2,4-dinitrophenyl)amino-4-octadecen-3-ol

Chemical Property:

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Technology Process of (2S,3R,4Z)-1-(5a-carba-β-D-glucopyranosylamino)-2-(2,4-dinitrophenyl)amino-4-octadecen-3-ol

There total 17 articles about (2S,3R,4Z)-1-(5a-carba-β-D-glucopyranosylamino)-2-(2,4-dinitrophenyl)amino-4-octadecen-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 142789-89-7
(1R,3R,6R,10S)-10-hydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

: 162119-28-0
(2S,3R,4Z)-1-(5a-carba-β-D-glucopyranosylamino)-2-(2,4-dinitrophenyl)amino-4-octadecen-3-ol

Guidance literature:: Multi-step reaction with 10 steps

1: pyridine / 1 h / Ambient temperature

2: 0.05M osmium tetraoxide/tert-butanol, N-methylmorpholine N-oxide / acetone; H₂O / 2 h / Ambient temperature

3: pyridine / 1 h at -15 deg C, 2 h at room temp.

4: pyridine / 8 h / Ambient temperature

5: 84 percent / sodium azide / dimethylformamide; H₂O / 2 h / 120 °C

6: 1M sodium methoxide / methanol; CH₂Cl₂ / 2 h / Ambient temperature

7: hydrogen / Raney nickel T-4 / ethanol / 5 h / Ambient temperature

8: 53 percent / propan-2-ol / 120 h / 120 °C

9: 1M tetrabutylammonium fluoride / tetrahydrofuran / 2 h / Ambient temperature

10: 80percent aq. acetic acid / 1 h / 90 °C

With pyridine; osmium(VIII) oxide; sodium azide; tetrabutyl ammonium fluoride; hydrogen; sodium methylate; acetic acid; 4-methylmorpholine N-oxide; tert-butyl alcohol; Raney nickel T-4; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; isopropyl alcohol; acetone;

Reference yield:

: 796850-28-7
(2R,4aR,6R,7S,8R,8aR)-6-Azido-2-phenyl-hexahydro-benzo[1,3]dioxine-7,8-diol

: 162119-28-0
(2S,3R,4Z)-1-(5a-carba-β-D-glucopyranosylamino)-2-(2,4-dinitrophenyl)amino-4-octadecen-3-ol

Guidance literature:: Multi-step reaction with 4 steps

1: hydrogen / Raney nickel T-4 / ethanol / 5 h / Ambient temperature

2: 53 percent / propan-2-ol / 120 h / 120 °C

3: 1M tetrabutylammonium fluoride / tetrahydrofuran / 2 h / Ambient temperature

4: 80percent aq. acetic acid / 1 h / 90 °C

With tetrabutyl ammonium fluoride; hydrogen; acetic acid; Raney nickel T-4; In tetrahydrofuran; ethanol; isopropyl alcohol;

Reference yield:

: 163218-37-9
Benzoic acid (2R,4aR,8R,8aR)-2-phenyl-4a,5,8,8a-tetrahydro-4H-benzo[1,3]dioxin-8-yl ester

: 162119-28-0
(2S,3R,4Z)-1-(5a-carba-β-D-glucopyranosylamino)-2-(2,4-dinitrophenyl)amino-4-octadecen-3-ol

Guidance literature:: Multi-step reaction with 9 steps

1: 0.05M osmium tetraoxide/tert-butanol, N-methylmorpholine N-oxide / acetone; H₂O / 2 h / Ambient temperature

2: pyridine / 1 h at -15 deg C, 2 h at room temp.

3: pyridine / 8 h / Ambient temperature

4: 84 percent / sodium azide / dimethylformamide; H₂O / 2 h / 120 °C

5: 1M sodium methoxide / methanol; CH₂Cl₂ / 2 h / Ambient temperature

6: hydrogen / Raney nickel T-4 / ethanol / 5 h / Ambient temperature

7: 53 percent / propan-2-ol / 120 h / 120 °C

8: 1M tetrabutylammonium fluoride / tetrahydrofuran / 2 h / Ambient temperature

9: 80percent aq. acetic acid / 1 h / 90 °C

With pyridine; osmium(VIII) oxide; sodium azide; tetrabutyl ammonium fluoride; hydrogen; sodium methylate; acetic acid; 4-methylmorpholine N-oxide; tert-butyl alcohol; Raney nickel T-4; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; isopropyl alcohol; acetone;