N-dimesitylfluorogermyl-N-tri-t-butyl-2,4,6-phenylamine

Base Information

• Chemical Name: N-dimesitylfluorogermyl-N-tri-t-butyl-2,4,6-phenylamine
• CAS No.: 143367-75-3
• Molecular Formula: C₃₆H₅₂FGeN
• Molecular Weight: 590.404
• Mol file: 143367-75-3.mol

Synonyms:

Chemical Property of N-dimesitylfluorogermyl-N-tri-t-butyl-2,4,6-phenylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-dimesitylfluorogermyl-N-tri-t-butyl-2,4,6-phenylamine

There total 2 articles about N-dimesitylfluorogermyl-N-tri-t-butyl-2,4,6-phenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

dimesityldifluorogermane (96481-36-6) + 2,4,6-tri-t-butylanilidolithium (102745-24-4) → N-dimesitylfluorogermyl-N-tri-t-butyl-2,4,6-phenylamine (143367-75-3)

Guidance literature:

In benzene; under inert gas; addn. of soln. of C6H2(C4H9)3NHLi (1.61 mmol) in pentane to soln. of (C6H2(CH3)3)2GeF2 (1.61 mmol) in benzene; warming for 30 min to 40-50°C;; filtering, evapg solvents from filtrate; washing with pentane (2 times);;

Reference yield:

dimesityldifluorogermane (96481-36-6) + 2,4,6-tri-t-butylanilidolithium (102745-24-4) → bis(tri-tert-butyl-phenylamino)dimesitylgermane + N-dimesitylfluorogermyl-N-tri-t-butyl-2,4,6-phenylamine (143367-75-3)

Guidance literature:

In benzene; Mes2GeF2 added to aminolithium, heated to 100°C;

Reference yield:

N-dimesitylfluorogermyl-N-tri-t-butyl-2,4,6-phenylamine (143367-75-3) → dimesityldifluorogermane (96481-36-6)

Guidance literature:

In benzene; byproducts: C6H2(CH3)3NH2; investigation of thermal decompn. in a sealed tube (18 h, 150-160°C); detected by 1H-NMR and gas chromy.; formation of 43% (C6H2(CH3)3)2GeF2 and 57% C6H2(CH3)3NH2;;

upstream raw materials:

dimesityldifluorogermane

2,4,6-tri-t-butylanilidolithium

Downstream raw materials:

dimesityldimethoxygermane

dimesityldifluorogermane