Technology Process of Germane, dimethoxybis(2,4,6-trimethylphenyl)-
There total 2 articles about Germane, dimethoxybis(2,4,6-trimethylphenyl)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
methanol; triethylamine;
In
benzene;
byproducts: HCl; (Ar or N2), dry solvents; addn. of MeOH and excess of Et3N to a soln. of the Ge-compd. in benzene, standing in a Schlenk tube at 40°C (3 h);; concn. (reduced pressure), filtration, concn. of filtrate (0.01 mm Hg), recrystn. in the cold (C6H6); elem. anal.;;
- Guidance literature:
-
In
benzene-d6;
addn. of CH3OH to soln. of (C6H2(CH3)3)2Ge(F)N(H)C6H2(C(CH3)3)3 (0.033 mmol) in C6D6 at 20°C (1 wk);; formation of 25% (C6H2(CH3)3)2Ge(OCH3)2, detected by 19F- and 1H-NMR;;
- Guidance literature:
-
With
hydrogen fluoride;
In
tetrahydrofuran;
byproducts: methanol; (Ar or N2), dry solvents; addn. of excess of HF (40%) to a soln. of the Ge-compd. in THF, stirring at 30°C (30 min);; extn. (benzene), drying (Na2SO4, 12 h), concn. (reduced pressure), redissolving (THF), drying (Na2SO4, 2 h), concn. (reduced pressure), crystn. (benzene); elem. anal.;;
