(C₆H₅)4As⁽¹⁺⁾*(CH₃)Ir(CO)2I₃^(1-)=[(C₆H₅)4As][(CH₃)Ir(CO)2I₃]

Base Information

Chemical Name:(C₆H₅)4As⁽¹⁺⁾*(CH₃)Ir(CO)2I₃^(1-)=[(C₆H₅)4As][(CH₃)Ir(CO)2I₃]
CAS No.:36542-09-3
Molecular Formula:C₃H₃I₃IrO₂*C₂₄H₂₀As
Molecular Weight:1027.33
Hs Code.:

(C<sub>6</sub>H<sub>5</sub>)4As<sup>(1+)</sup>*(CH<sub>3</sub>)Ir(CO)2I<sub>3</sub><sup>(1-)</sup>=[(C<sub>6</sub>H<sub>5</sub>)4As][(CH<sub>3</sub>)Ir(CO)2I<sub>3</sub>]

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Chemical Property of (C₆H₅)4As⁽¹⁺⁾*(CH₃)Ir(CO)2I₃^(1-)=[(C₆H₅)4As][(CH₃)Ir(CO)2I₃]

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Technology Process of (C₆H₅)4As⁽¹⁺⁾*(CH₃)Ir(CO)2I₃^(1-)=[(C₆H₅)4As][(CH₃)Ir(CO)2I₃]

There total 2 articles about (C₆H₅)4As⁽¹⁺⁾*(CH₃)Ir(CO)2I₃^(1-)=[(C₆H₅)4As][(CH₃)Ir(CO)2I₃] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 29629-79-6,1162649-21-9
Ph₄As[Ir(CO)₂I₂]

: 74-88-4
methyl iodide

: 259794-29-1,36542-09-3
cis,fac-[Ir(CO)2I₃Me]AsPh₄

Guidance literature:: In neat (no solvent); Ir-complex was dissolved in methyl iodide, stirred under N2 for 1 h; MeI was removed in vacuo, recrystd. from CH2Cl2-Et2O, dried in vacuo; elem. anal.;
DOI:10.1021/ja039464y

Reference yield:

: 29629-79-6,1162649-21-9
(C₆H₅)4As⁽¹⁺⁾*Ir(CO)2I₂^(1-)=[(C₆H₅)4As][Ir(CO)2I₂]

: 36542-09-3,259794-29-1
(C₆H₅)4As⁽¹⁺⁾*(CH₃)Ir(CO)2I₃^(1-)=[(C₆H₅)4As][(CH₃)Ir(CO)2I₃]

Guidance literature:: With CH₃I; In dichloromethane; under Ar; react. of Ir-complex and large excess of alkyl iodide in CH2Cl2 in a stainless steel (Fisher-Porter) tube at 5-35°C; or varying amts. of MeI at 25°C; not isolated, react. monitored by IR spect.; Kinetics;
DOI:10.1021/om00020a039

Reference yield: 84.0%

: 259794-29-1,36542-09-3
cis,fac-[Ir(CO)2I₃Me]AsPh₄

: [(Ir(CO)I₃Me)2](AsPh₄)2

Guidance literature:: With CH₃I; In further solvent(s); CH3I added to soln. of Ir complex in C6H5Cl, mixt. refluxed under N2 for5 d; cooled to room temp., liquid removed by pipet, solid washed with Et2O, dried at 100°C under vac. overnight; elem. anal.;
DOI:10.1021/ic8017858