1,1'-bis(pentafluorophenyl)zirconocene dimethide

Base Information

• Chemical Name: 1,1'-bis(pentafluorophenyl)zirconocene dimethide
• CAS No.: 602335-46-6
• Molecular Formula: C₂₄H₁₄F₁₀Zr
• Molecular Weight: 583.583
• Mol file: 602335-46-6.mol

Synonyms:

Chemical Property of 1,1'-bis(pentafluorophenyl)zirconocene dimethide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-bis(pentafluorophenyl)zirconocene dimethide

There total 1 articles about 1,1'-bis(pentafluorophenyl)zirconocene dimethide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

dichlorobis[η(5)-(pentafluorophenyl)cyclopentadienyl]zirconium(IV) (184481-08-1) + methyllithium (917-54-4) → 1,1'-bis(pentafluorophenyl)zirconocene dimethide (602335-46-6)

Guidance literature:

In toluene; (N2); stirring a mixt. of zirconium complex with lithium compd. in toluene at 25°C for 18 h in the dark; evapn., recrystn. (hexanes);

DOI:10.1021/om030171n

Reference yield: 85.0%

1,1'-bis(pentafluorophenyl)zirconocene dimethide (602335-46-6) + trityl chloride (76-83-5) → [(C6F5C5H4)2Zr(CH3)Cl] (651299-97-7)

Guidance literature:

In benzene; byproducts: Ph3CCH3; N2 glovebox; Zr complex was treated with Ph3CCl (1-1.1 equiv.) in benzene at 60°C for 18 h; evapd.; recrystn. from hexane under Ar;

DOI:10.1021/om0305014

Reference yield: 81.0%

1,1'-bis(pentafluorophenyl)zirconocene dimethide (602335-46-6) + tris(pentafluorophenyl)borate (1109-15-5) → (C6F5C5H4)2ZrCH3(1+)*CH3B(C6F5)3(1-)=(C6F5C5H4)2ZrCH3CH3B(C6F5)3 (602335-50-2)

Guidance literature:

In toluene; (N2); stirring a soln. of zirconium complex and boron compd. in toluene for 5 min at 25°C; evapn., trituration with pentane, filtration, drying in vac.; elem. anal.;

DOI:10.1021/om030171n

upstream raw materials:

dichlorobis[η(5)-(pentafluorophenyl)cyclopentadienyl]zirconium(IV)

methyllithium

Downstream raw materials:

dichlorobis[η(5)-(pentafluorophenyl)cyclopentadienyl]zirconium(IV)

[(C₆F₅C₅H₄)2Zr(CH₃)Cl]

(C₆F₅C₅H₄)2ZrCH₃⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-)=(C₆F₅C₅H₄)2ZrCH₃CH₃B(C₆F₅)3