[(η6-C6Me6)RuCl2(DMPP)]

Base Information

• Chemical Name: [(η6-C6Me6)RuCl2(DMPP)]
• CAS No.: 265323-69-1
• Molecular Formula: C₂₄H₃₁Cl₂PRu
• Molecular Weight: 522.46

Synonyms:

Chemical Property of [(η6-C6Me6)RuCl2(DMPP)]

Chemical Property:

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Technology Process of [(η6-C6Me6)RuCl2(DMPP)]

There total 1 articles about [(η6-C6Me6)RuCl2(DMPP)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.93%

(RuCl2(η6-C6Me6))2 (67421-02-7,847615-12-7) + 3,4-dimethyl-1-phenylphosphole (30540-36-4) → [(η6-C6Me6)RuCl2(DMPP)] (265323-69-1)

Guidance literature:

In dichloromethane; to suspn. of Ru-complex in CH2Cl2 was added phosphine via syringe, mixt. was stirred under N2 at ambient temp. for 4 h; vol. was reduced on rotary evaporator, ether was added, filtered, washed with ether, dried under vac.; elem. anal.;

DOI:10.1080/00945710009351770

Reference yield: 85.9%

sodium hexaflorophosphate + [(η6-C6Me6)RuCl2(DMPP)] (265323-69-1) + acetonitrile (75-05-8,26809-02-9) → Ru(CH3CN)Cl(C6(CH3)6)((C6H5)P(CH3)2C4H2)(1+)*PF6(1-)=RuCl(CH3CN)(C6(CH3)6)((C6H5)P(CH3)2C4H2)PF6 (268559-25-7)

Guidance literature:

In dichloromethane; acetonitrile; byproducts: NaCl; to soln. of Ru-complex in MeCN and CH2Cl2 was added NaPF6, soln. was stirred under N2 at ambient temp. for 24 h; soln. was filtered, reduced to dryness on rotary evaporator, extracted with acetone, filtered, filtrate vol. was reduced on rotary evaporator, ether was added, filtered, washed with ether, dried under vac. at ambient temp.; elem. anal.;

DOI:10.1080/00945710009351771

Reference yield: 80.0%

[(η6-C6Me6)RuCl2(DMPP)] (265323-69-1) + silver trifluoromethanesulfonate (2923-28-6) + Diphenylvinylphosphine (2155-96-6) → [(η6-C6(CH3)6)Ru(2-diphenylphosphino-5,6-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-5-ene)Cl](CF3SO3) (561042-85-1,561042-88-4)

Guidance literature:

In dichloromethane; addn. of solid silver triflate (1 equiv.) to dichloromethane soln. of Rucomplex in the dark, purging with N2, addn. of diphenylvinyl phosphine, stirring for 72 h under N2 at ambient temp.; filtration (celite), vol. reduction, pptn. by addn. of ether, filtration, washing with ether, drying under vac. at ambient temp.; elem. anal.;

DOI:10.1016/S0022-328X(02)02216-7

upstream raw materials:

(RuCl2(η6-C6Me6))2

3,4-dimethyl-1-phenylphosphole

Downstream raw materials:

[RuCl(C₆H₅PC₄H₂(CH₃)2)(C₆(CH₃)6)(CH₂CHCH₂P(C₆H₅)2)]⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₆H₅PC₄H₂(CH₃)2)(C₆(CH₃)6)(CH₂CHCH₂P(C₆H₅)2)]PF₆

Ru(CH₃CN)Cl(C₆(CH₃)6)((C₆H₅)P(CH₃)2C₄H₂)⁽¹⁺⁾*PF₆^(1-)=RuCl(CH₃CN)(C₆(CH₃)6)((C₆H₅)P(CH₃)2C₄H₂)PF₆

[(η6-C6(CH3)6)Ru(2-diphenylphosphino-5,6-dimethyl-7-phenyl-7-phosphabicyclo[2.2.1]hept-5-ene)Cl](CF3SO3)

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