{PdCl₂((C₆H₅)2PCH₂C₅H₉O)2}

Base Information

• Chemical Name: {PdCl₂((C₆H₅)2PCH₂C₅H₉O)2}
• CAS No.: 150737-23-8
• Molecular Formula: C₃₆H₄₂Cl₂O₂P₂Pd
• Molecular Weight: 746.002
• Mol file: 150737-23-8.mol

Synonyms:

Chemical Property of {PdCl₂((C₆H₅)2PCH₂C₅H₉O)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {PdCl₂((C₆H₅)2PCH₂C₅H₉O)2}

There total 1 articles about {PdCl₂((C₆H₅)2PCH₂C₅H₉O)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.3%

dichloro(cycloocta-1,5-diene)palladium (II) (12107-56-1) + Diphenyl(tetrahydropyranyl-2-methyl)phosphan (135492-09-0) → cis-dichlorobis{diphenyl(tetrahydropyranyl-2-methyl)phosphane-P}palladium(II) (150737-23-8,135483-93-1)

Guidance literature:

In dichloromethane; byproducts: 1,5-cyclooctadiene; under Ar, addn. of soln. of phosphane to soln. of complex within 0.5 h, stirring for 2 h; evapn. of solvent in vac., stirring of residue in Et2O-pentane overnight, centrifugation, sepn. of powder, drying in vac., elem. anal.;

Reference yield: 98.0%

cis-bis{diphenyl(tetrahydropyran-2-ylmethyl)phosphane-O,P}palladium(II)-bis(perchlorate) + {PdCl2((C6H5)2PCH2C5H9O)2} (150737-23-8,135483-93-1) → cis-chlorobis{diphenyl(tetrahydropyran-2-ylmethyl)phosphane-P;O',P'}palladium(II)-perchlorate (135484-02-5)

Guidance literature:

In dichloromethane; equimolar amts. (0.33 mmol) of the educts were dissolved in dry CH2Cl2 and stirred for 5 min (exclusion of air);; the solvent was removed in vac., the residue stirred with diethyl ether/n-pentane (1:1) for about 12 h; the the solvent was decanted and the residue dried in vac.; elem. anal.;;;

Reference yield: 94.0%

silver perchlorate monohydrate (14242-05-8) + {PdCl2((C6H5)2PCH2C5H9O)2} (150737-23-8,135483-93-1) → cis-bis{diphenyl(tetrahydropyran-2-ylmethyl)phosphane-O,P}palladium(II)-bis(perchlorate)

Guidance literature:

In acetone; byproducts: AgCl; a supension of AgClO4 (1.64 mmol) was dropwise added to a suspension of PdCl2(Ph2PCH2C5H9O)2 (0.78 mmol), both in acetone, within 10 min in the dark; the mixt. was stirred for 1 h in the dark;; after filtration from AgCl, the solvent was removed in vac.; the residue was stirred with diethyl ether/n-pentane (1:1) for about 12 h; then the solvent was decanted and the residue dried in vac.; elem. anal.;;

upstream raw materials:

dichloro(cycloocta-1,5-diene)palladium (II)

Diphenyl(tetrahydropyranyl-2-methyl)phosphan

Downstream raw materials:

trans-chlorobis{diphenyl(tetrahydropyranyl-2-methyl)phosphane-P;O',P'}palladium(II) perchlorate

cis-chlorobis{diphenyl(tetrahydropyran-2-ylmethyl)phosphane-P;O',P'}palladium(II)-perchlorate