[Ni(η3-methylallyl)(κ1P-diisopropylallylphosphine)2]B(C6H3(CF3)2-3,5)4

Base Information

• Chemical Name: [Ni(η3-methylallyl)(κ1P-diisopropylallylphosphine)2]B(C6H3(CF3)2-3,5)4
• CAS No.: 948041-20-1
• Molecular Formula: C₂₂H₄₅NiP₂*C₃₂H₁₂BF₂₄
• Molecular Weight: 1293.46
• Mol file: 948041-20-1.mol

Synonyms:

Chemical Property of [Ni(η3-methylallyl)(κ1P-diisopropylallylphosphine)2]B(C6H3(CF3)2-3,5)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(η3-methylallyl)(κ1P-diisopropylallylphosphine)2]B(C6H3(CF3)2-3,5)4

There total 1 articles about [Ni(η3-methylallyl)(κ1P-diisopropylallylphosphine)2]B(C6H3(CF3)2-3,5)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 2-methyl-3-bromo-1-propene (1458-98-6) + diisopropylallylphosphine + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [Ni(η3-methylallyl)(κ1P-diisopropylallylphosphine)2]B(C6H3(CF3)2-3,5)4 (948041-20-1)

Guidance literature:

In diethyl ether; (inert conditions); addn. of propene deriv. to slurry of nickel compd. in ether cooled in liquid N2/ethanol bath, warming to room temp., stirring for 1 h, addn. of borate deriv., stirring for 1 h, addn. of phosphine deriv., stirring for 15 min; filtration through celite, evapn., washing with petroleum ether, recrystn. (CH2Cl2/petroleum ether), filtration, washing with petroleum ether, drying in vac., elem. anal.;

DOI:10.1039/b705579j

upstream raw materials:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

2-methyl-3-bromo-1-propene

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate